SODIUM PERMANGANATE

SODIUM PERMANGANATE Basic information
Product Name:SODIUM PERMANGANATE
Synonyms:permanganatedesodium;Natriumpermanganat;Sodium permangannte;Sodium permanganate monohydrate, min. 98%;SodiuM perManganate, 40wt%;SodiuM perManganate solution 40 wt. % in H2O;permanganatedesodium(french);permanganatosodico
CAS:10101-50-5
MF:MnNaO4
MW:141.925419
EINECS:233-251-1
Product Categories:OthersMetal and Ceramic Science;Oxidation;Salts;Sodium Salts;Synthetic Reagents
Mol File:10101-50-5.mol
SODIUM PERMANGANATE Structure
SODIUM PERMANGANATE Chemical Properties
Melting point 170°C
Boiling point 100 °C
density 1.391 g/mL at 25 °C
vapor pressure 0Pa at 25℃
form red-black hygroscopic crystals
Water Solubility very soluble H2O; decomposed by alcohol [MER06]
Sensitive Hygroscopic
Merck 13,8727
CAS DataBase Reference10101-50-5(CAS DataBase Reference)
EPA Substance Registry SystemSodium permanganate (10101-50-5)
Safety Information
Hazard Codes O,C,N
Risk Statements 8-34-50/53-22
Safety Statements 17-26-36/37/39-45-61
RIDADR UN 1503 5.1/PG 2
WGK Germany 3
RTECS SD6650000
HazardClass 5.1
PackingGroup II
HS Code 28416900
Hazardous Substances Data10101-50-5(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
SODIUM PERMANGANATE Usage And Synthesis
Chemical Propertiesdark grey to purple to greenish black or black
Chemical PropertiesA reddish-black or purple crystalline solid.
UsesSodium permanganate (NaMnO4) is a purple crystal that is soluble in water and is used as an oxidizing agent, disinfectant, and bactericide and as an antidote for morphine poisoning.
UsesOxidizing agent; disinfectant; bactericide; man- ufacture of saccharin; antidote for poisoning by morphine, curare, and phosphorus.
General DescriptionA purplish colored crystalline solid. Noncombustible but accelerates the burning of combustible material. If the combustible material is finely divided the mixture may be explosive. May spontaneously ignite in contact with liquid combustible materials. Contact with sulfuric acid may cause fires or explosions. Used in medicine, as a disinfectant, and for many other uses.
Air & Water ReactionsSoluble in water.
Reactivity ProfileAcetic acid or acetic anhydride can explode with permanganates if not kept cold [Von Schwartz 1918 p. 34]. Explosions can occur when permanganates that have been treated with sulfuric acid come in contact with benzene, carbon disulfide, diethyl ether, ethyl alcohol, petroleum, or organic matter.
HazardDangerous fire risk in contact with organic materials, strong oxidizing agent.
Health HazardInhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire HazardThese substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.
Flammability and ExplosibilityNotclassified
Safety ProfileProbably a severe irritant to the skin, eyes, and mucous membranes. A powerful oxidizer and fire hazard. Explosive reaction with acetic acid, acetic anhydride. Reacts vigorously with combustibles. When heated to decomposition it emits toxic fumes of Na2O. See also MANGANESE COMPOUNDS, PERMANGANATES, and POTASSIUM PERMANGANATE.
Potential ExposureUsed in medicine, as a disinfectant, and for many other uses: an oxidizer in reaction for making other chemicals, etchant for electronic boards; an antidote drug for chemical poisons
ShippingUN1503 Sodium Permanganate, Hazard Class: 5.1; Labels: 5.1-Oxidizer. PG2
IncompatibilitiesOxidizers accelerates the burning of combustible material. Some may decompose explosively when heated or involved in a fire. May ignite combustibles: wood, paper, oil, organic matter, clothing, etc. Contact with finely divided metal may by explosive. May spontaneously ignite in contact with liquid combustible materials, hydrocarbons, benzene, fuels, diethyl ether, carbon disulfide. Incompatible with acetic anhydride, acetic acid. Contact with sulfuric acid may cause fires or explosions. Heat or contamination may cause explosion.
Waste DisposalGenerators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers.
SODIUM PERMANGANATE Preparation Products And Raw materials
Raw materialsManganese dioxide
permanganic acid Sodium sulfide Sodium sulfate Sodium sulfite Manganese dioxide Sodium thiosulfate SODIUM MANGANATE Manganese(II)dihydoxide SODIUM PERMANGANATE MONOHYDRATE Sodium silicate Permanganate Sodium hydroxide POTASSIUM MANGANATE Sodium carbonate MANGANESE (II) OXIDE Manganese SODIUM PERMANGANATE

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