3-(Trifluoromethyl)phenylboronic acid

3-(Trifluoromethyl)phenylboronic acid Basic information
Product Name:3-(Trifluoromethyl)phenylboronic acid
Synonyms:a,a,a-Trifluoro-m-tolueneboronic acid;α,α,α-Trifluoro-m-tolueneboronic Acid;3-Trifluoromethylphenylboronic acid ,98%;m-Trufluoromethylboronic Acid;3-(Trifluoromethyl)p;alpha,alpha,alpha-Trifluoro-m-tolueneboronic Acid alpha,alpha,alpha-Trifluoro-m-tolylboronic Acid;3-trifluoroMethyl-phenoxy-boronic acid;3-(TRIFLUOROMETHYL)PHENYLBORONIC ACID
CAS:1423-26-3
MF:C7H6BF3O2
MW:189.93
EINECS:604-284-2
Product Categories:Substituted Boronic Acids;Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronic Acid;Aryl;Halogenated;blocks;BoronicAcids;FluoroCompounds;Organoborons;B (Classes of Boron Compounds);Boronic Acids;Boronic Acids & Esters;Pyridines ,Halogenated Heterocycles ,Heterocyclic Acids;Phenyls & Phenyl-Het;Boronate Ester;Potassium Trifluoroborate
Mol File:1423-26-3.mol
3-(Trifluoromethyl)phenylboronic acid Structure
3-(Trifluoromethyl)phenylboronic acid Chemical Properties
Melting point 163-166 °C (lit.)
Boiling point 268.2±50.0 °C(Predicted)
density 1.36±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility slightly sol. in Methanol
pka7.55±0.10(Predicted)
form Powder
color White to pale yellow
BRN 6084746
InChIKeyWOAORAPRPVIATR-UHFFFAOYSA-N
CAS DataBase Reference1423-26-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
10-21
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
3-(Trifluoromethyl)phenylboronic acid Usage And Synthesis
Chemical PropertiesWhite to pale yellow powder
Usessuzuki reaction
UsesReactant involved in:
  • Suzuki-Miyaura cross-coupling reactions
  • Aerobic oxidative cross-coupling
  • Microwave-assisted Petasis reactions
  • Rhodium-catalyzed addition reactions
  • Syntehsis of biologically active molecules
3-(Trifluoromethyl)phenylboronic acid Preparation Products And Raw materials
Preparation Products3-(TRIFLUOROMETHYL)BENZOPHENONE-->3-TRIFLUOROMETHYLPHENYLBORONIC ACID, PINACOL ESTER-->N-phenyl-3-(trifluoromethyl)aniline-->6-(3-Trifluoromethylphenyl)pyridine-3-carboxaldehyde-->4-FLUORO-3'-TRIFLUOROMETHYLBIPHENYL-->methyl 5-(3-(trifluoromethyl)phenyl)pyridine-3-carboxylate-->2-Fluoro-4-(3-trifluoroMethylphenyl)benzoic acid-->N-[3-(TrifluoroMethyl)phenyl]benzenesulfonaMide, 97%-->1-Azido-3-(trifluoroMethyl)benzene solution
4-Tolylboronic acid 5-Methyl-1H-benzotriazole Benzotrifluoride Ethyl 2-(Chlorosulfonyl)acetate 4-Aminobenzotrifluoride 3-(Trifluoromethyl)benzaldehyde Ascoric Acid 2-(Trifluoromethyl)benzoic acid Folic acid Phenylboronic acid Trifluoromethyl 3,5-Dimethylphenylboronic acid 4-(Trifluoromethyl)benzaldehyde 4-(TRIFLUOROMETHYL)PHENYLBORONIC ACID,P-(TRIFLUOROMETHYL)PHENYLBORONIC ACID Lithium triflate Phenylmethylsulfonyl fluoride 2-Methylbenzotrifluoride Citric acid

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