ChemicalBook Product Catalog Organic Chemistry Amides Naphthenic amines derivatives Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine

Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine

Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine Basic information
Uses
Product Name:Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine
Synonyms:trans-N,N;trans-(1R,2R)-N,N'-BisMethyl-1,2-cyclohexanedia;1,2-CyclohexanediaMine,N1,N2-diMethyl-, (1R,2R)-rel-;trans-N,N'-DiMethylcyclohexane-1,2-diaMin;rel-(1R,2R)-N1,N2-DiMethylcyclohexane-1,2-diaMine;trans-N1,N2-DiMethylcyclohexane-1,2-diaMine;(1R,2R)-rel-N1,N2-DiMethylcyclohexane-1,2-diaMine;TRANS-1,2-BIS(METHYLAMINO)CYCLOHEXANE
CAS:67579-81-1
MF:C8H18N2
MW:142.24
EINECS:
Product Categories:Chiral Nitrogen;DACH&Trost Series;Chiral Reagents;Miscellaneous Reagents
Mol File:67579-81-1.mol
Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine Structure
Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine Chemical Properties
Melting point 4°C
Boiling point 83 °C / 13mmHg
density 0.89
refractive index n20/D1.472(lit.)
Fp 60℃
storage temp. Keep in dark place,Inert atmosphere,2-8°C
pka11.04±0.40(Predicted)
form liquid
color colorless to pale yellow
Sensitive air sensitive
InChIKeyJRHPOFJADXHYBR-HTQZYQBOSA-N
CAS DataBase Reference67579-81-1(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 36/37/38-34-22
Safety Statements 26-36/37/39-45
RIDADR 2735
WGK Germany 3
HazardClass 8
PackingGroup Ⅱ
HS Code 2921309990
MSDS Information
Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine Usage And Synthesis
UsesTrans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine used with CuI to form a general and highly efficient catalyst for the N-amidation of aryl and heteroaryl iodides, bromides and in some cases, unactivated aryl chlorides. The catalyst system is also used for the N-arylation of indoles.
DescriptionTrans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine is a useful research chemical for organic synthesis and other chemical processes.
Usestrans-N,N′-dimethylcyclohexane-1,2-diamine can be used as a ligand in the synthesis of the following products via copper catalyzed C-N coupling reactions:
  • vinylsulfoximines obtained from NH sulfoximes and vinyl bromides
  • N-arylpyridones obtained via reaction between 2-substituted pyridines and aryl halides
  • N-aryl amines obtained via reaction between amines and aryl iodides/aryl bromides
Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine Preparation Products And Raw materials
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (4AR,8AR)-DECAHYDRO-QUINOXALINE [3H]U-69593 (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) (-)-(1S,2R)-CIS-3,4-DICHLORO-N-METHYL-N-[2-(1-PYRROLIDINYL)-CYCLOHEXYL]-BENZENEACETAMIDE TARTRATE (+/-)-TRANS-1,2-BIS(CHLOROACETAMIDO)CYCLOHEXANE (+/-)-TRANS-1,2-BIS(THIOACETATEACETAMIDO)CYCLOHEXANE Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine (+)-U-50488 HYDROCHLORIDE trans-(-3,4-Dichloro-N-methyl-N-[2-(1-pyrrolidinyl)cyclohexyl]benzeneacetamidehydrochloride (1R,2R)-N,N,N''N''-TETRAMETHYL-1,2-CYCLOHEXANEDIAMINE TRANS-1,2-DIAMINOCYCLOHEXANE-N,N,N',N'-TETRAACETIC ACID MONOHYDRATE 1,2-Cyclohexylenedinitrilotetraacetic acid (+/-)-(5ALPHA,7ALPHA,8BETA)-3,4-DICHLORO-N-METHYL-N-(7-[1-PYRROLIDINYL]-1-OXASPIRO[4.5]DEC-8-YL)BENZENEACETAMIDE MESYLATE (+/-)-TRANS-1,2-BIS(2-MERCAPTOACETAMIDO)CYCLOHEXANE N,N'-Dimethyl-1,2-cyclohexanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) [3H]CI-977
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