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| | 2-HYDROXYCYCLOHEXANONE DIMER Basic information |
| | 2-HYDROXYCYCLOHEXANONE DIMER Chemical Properties |
| Melting point | 100-107 °C(lit.) | | Boiling point | 83-86 °C13 mm Hg(lit.) | | Fp | 175 °F | | storage temp. | 2-8°C | | form | Powder | | color | Off-white | | Water Solubility | Partly miscible in water. |
| Hazard Codes | F,Xi | | Risk Statements | 11-36/37/38 | | Safety Statements | 16-26-36 | | RIDADR | UN 1325 4.1/PG 3 | | WGK Germany | 3 | | F | 9-21 | | HazardClass | 4.1 | | PackingGroup | III | | HS Code | 29144090 |
| | 2-HYDROXYCYCLOHEXANONE DIMER Usage And Synthesis |
| Chemical Properties | Off-white powder | | Uses | Reactant involved in:• ;Synthesis of substrated for tin tetrachloride mediated fragmentation to produce ynones and ynoates1• ;Tandem oxidation coupling reactions with diamines2• ;Asymmetric allylic alkylation of enolates3• ;Formate reduction of allylic carbonates for polypropionate systems4 | | Uses | It is a reactant involved in the synthesis of substrates for tin tetrachloride mediated fragmentation to produce ynones and ynoates, tandem oxidation coupling reactions with diamines, asymmetric allylic alkylation of enolates and formate reduction of allylic carbonates for polypropionate systems. | | Uses | Reactant involved in:
- Synthesis of substrated for tin tetrachloride mediated fragmentation to produce ynones and ynoates
- Tandem oxidation coupling reactions with diamines
- Asymmetric allylic alkylation of enolates
- Formate reduction of allylic carbonates for polypropionate systems
| | Definition | ChEBI: 2-hydroxycyclohexan-1-one is a secondary alpha-hydroxy ketone and a hydroxycyclohexanone. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 51, p. 130, 1986 DOI: 10.1021/jo00352a002
Synthetic Communications, 25, p. 3141, 1995 DOI: 10.1080/00397919508015463
Tetrahedron Letters, 36, p. 3031, 1995 DOI: 10.1016/0040-4039(95)00419-D |
| | 2-HYDROXYCYCLOHEXANONE DIMER Preparation Products And Raw materials |
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