2-Thienylmagnesium bromide solution

2-Thienylmagnesium bromide solution Basic information
Product Name:2-Thienylmagnesium bromide solution
Synonyms:2-ThienylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal;magnesium,2H-thiophen-2-ide,bromide;Bromo-2-thienylmagnesium;THIOPHEN-2-YL-MAGNESIUM BROMIDE 1.0M;2-Thienylmagnesium bromide solution, 1.0M in tetrahydrofuran;thiophen-2-yl-magnesium bromide solution;2-Thienylmagnesium bromide solution;2-Thienylmagnesium bromide, 1M solution in THF, AcroSeal
CAS:5713-61-1
MF:C4H3BrMgS
MW:187.34062
EINECS:
Product Categories:Grignard Reagents;Heteroaryl;Organometallic Reagents
Mol File:5713-61-1.mol
2-Thienylmagnesium  bromide  solution Structure
2-Thienylmagnesium bromide solution Chemical Properties
Boiling point 65 °C
density 1.011 g/mL at 25 °C
Fp −6 °F
form Solution
color Yellow to orange to brown
Safety Information
Hazard Codes F,C,Xn
Risk Statements 11-14-19-22-34-40-36/37
Safety Statements 16-26-36/37/39-45-36/37
RIDADR UN 2924 3/PG 2
WGK Germany 1
HS Code 29349990
MSDS Information
2-Thienylmagnesium bromide solution Usage And Synthesis
Chemical PropertiesYellow to orange to brown liquid
Uses2-Thienylmagnesium bromide is a Grignard reagent that can be used as a reactant to synthesize:
  • 1-(2-thienyl)-carbinols by condensation reaction with aldehydes. Carbinols are further dehydrated to form 2-thienyl olefins.
  • Thiophene-functionalized polystyrene macromonomer (ThPStM), which is employed as a key intermediate to synthesize polystyrene-graft-polythiophene (PSt-g-PTh) via a combination of atom transfer radical polymerization (ATRP) and Grignard reaction.
  • Thienylene oligomers, which are used as conducting polymers and as potential OLEDs.

N-OCTYLMAGNESIUM BROMIDE 2-BUTENYLMAGNESIUM CHLORIDE 1-PROPYNYLMAGNESIUM BROMIDE 3-METHOXYPHENYLMAGNESIUM BROMIDE Hexylmagnesium chloride 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 1-PROPENYLMAGNESIUM BROMIDE 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 2,5-DIMETHYLPHENYLMAGNESIUM BROMIDE CYCLOHEXYLMAGNESIUM BROMIDE 5-Chloro-2-MethoxyphenylMagnesiuM broMide, 0.50M in 2-MeTHF 1-METHYL-1-PROPENYLMAGNESIUM BROMIDE 2,4-DIMETHOXYPHENYLMAGNESIUM BROMIDE 1-NAPHTHYLMAGNESIUM BROMIDE 2-METHYLBENZYLMAGNESIUM CHLORIDE 2-NAPHTHYLMAGNESIUM BROMIDE 2,4-DIMETHYLPHENYLMAGNESIUM BROMIDE Magnesium

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