4-Methylbenzylsulfonyl chloride

4-Methylbenzylsulfonyl chloride Basic information
Product Name:4-Methylbenzylsulfonyl chloride
Synonyms:(4-Methylphenyl)methanesulfonyl chloride, 4-Methylbenzenemethanesulfonyl chloride, p-Methyl-α-toluenesulfonyl chloride, p-Tolylmethanesulfonyl chloride;^a-p-Xylenesulfonyl chloride, 97%;alpha-p-Xylenesulfonyl chloride, 97%;(4-Methylphenyl)methanesulfonyl chloride, TECH;4-Methylbenzylsulfon;BenzeneMethanesulfonylchloride, 4-Methyl-;4-Methylbenzylsulfonyl chloride 96%;P-TOLYL-METHANESULFONYL CHLORIDE
CAS:51419-59-1
MF:C8H9ClO2S
MW:204.67
EINECS:200-258-5
Product Categories:Phenyls & Phenyl-Het;Fluorobenzene;Sulphonyl Chlorides;Phenyls & Phenyl-Het;Sulphonyl Chlorides
Mol File:51419-59-1.mol
4-Methylbenzylsulfonyl chloride Structure
4-Methylbenzylsulfonyl chloride Chemical Properties
Melting point 76-80 °C
Boiling point 305.2±21.0 °C(Predicted)
density 1.325±0.06 g/cm3(Predicted)
storage temp. 2-8°C
Sensitive Moisture Sensitive
CAS DataBase Reference51419-59-1(CAS DataBase Reference)
Safety Information
Hazard Codes C,Xi
Risk Statements 22-34
Safety Statements 26-28-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup II
HS Code 29049090
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Methylbenzylsulfonyl chloride Usage And Synthesis
Uses4-Methylbenzylsulfonyl chloride is a useful reactant for the synthesis of (R)-1-alkyl-substituted tetrahydro-ss-carbolines.
Synthesis Reference(s)Tetrahedron Letters, 25, p. 4553, 1984 DOI: 10.1016/S0040-4039(01)81491-X
Methylene Chloride Chlorodimethylphenylsilane 4-Fluorobenzenesulfonyl chloride Calcium chloride Sodium chloride TRIFLUOROMETHANESULFONYL CHLORIDE 3-Nitrobenzenesulfonyl chloride alpha-Toluenesulfonyl chloride Choline chloride Methanesulfonyl chloride Tosyl chloride Benzenesulfonyl chloride 4-Nitrobenzenesulfonyl chloride Polyvinyl chloride Tris(hydroxymethyl)aminomethane Triphenylmethyl Chloride 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile 4-(Trifluoromethyl)benzene-1-sulfonyl chloride

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