ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Aromatic hydrocarbons 1-Methyl-4-(methylsulfonyl)-benzene

1-Methyl-4-(methylsulfonyl)-benzene

1-Methyl-4-(methylsulfonyl)-benzene Basic information
Product Name:1-Methyl-4-(methylsulfonyl)-benzene
Synonyms:1-Methansulfonyl-4-methylbenzen;1-Methansulfonyl-4-methylbenzene;1-Methyl-4-(methyl-sulphonyl)benzene;Benzene,1-methyl-4-(methylsulfonyl)-;Methyl 4-tolyl sulfone;p-Tolyl methyl sulfone;Sulfone, methyl p-tolyl;P-METHYL SULFONYL TOLUENE
CAS:3185-99-7
MF:C8H10O2S
MW:170.23
EINECS:221-682-8
Product Categories:Building Blocks;Chemical Synthesis;Boron, Nitrile, Thio,& TM-Cpds;Organic Building Blocks;Sulfones;Sulfur Compounds;3185-99-7;bc0001
Mol File:3185-99-7.mol
1-Methyl-4-(methylsulfonyl)-benzene Structure
1-Methyl-4-(methylsulfonyl)-benzene Chemical Properties
Melting point 85-89 °C(lit.)
Boiling point 140 °C / 3mmHg
density 1.2238 (rough estimate)
refractive index 1.5320 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color White to Almost white
BRN 607296
InChIKeyYYDNBUBMBZRNQQ-UHFFFAOYSA-N
CAS DataBase Reference3185-99-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-methyl-4-(methylsulfonyl)-(3185-99-7)
EPA Substance Registry SystemBenzene, 1-methyl-4-(methylsulfonyl)- (3185-99-7)
Safety Information
Hazard Codes Xn,F
Risk Statements 22-37/38-41
Safety Statements 26-36-24/25
WGK Germany 1
HazardClass IRRITANT
HS Code 29309090
MSDS Information
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1-Methyl-4-(methylsulfonyl)-benzene English
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1-Methyl-4-(methylsulfonyl)-benzene Usage And Synthesis
Chemical PropertiesWHITE TO LIGHT BEIGE CRYSTALLINE POWDER
Synthesis Reference(s)Tetrahedron Letters, 32, p. 2933, 1991 DOI: 10.1016/0040-4039(91)80653-N
The Journal of Organic Chemistry, 22, p. 1129, 1957 DOI: 10.1021/jo01360a621
1-Methyl-4-(methylsulfonyl)-benzene Preparation Products And Raw materials
Raw materialsSodium bicarbonate-->Sodium sulfite
Preparation ProductsThiamphenicol-->1-(BROMOMETHYL)-4-(METHYLSULFONYL)BENZENE-->2-Nitro-4-methylsulfonylbenzoic acid-->4-TOLUENESULFONYLACETIC ACID-->4-(METHYLSULFONYL)BENZONITRILE
DIMETHYL DIPHENYL SULFONE 4,4'-DICARBOXYLATE 4'-METHYL-2(P-TOLYL SULFONYL)ACETOPHENONE PHENYL P-TOLYL SULFONE 4-TOLUENESULFONYLACETIC ACID N-(p-Tolylsulfonylmethyl)formamide 2-(P-TOLUENESULFONYL)ACETOPHENONE 4-METHANESULFONYL-3-NITRO-BENZOIC ACID METHYL P-TOLUENESULPHONYLACETATE 4-Methylsulphonylbenzoic acid Tosylmethyl isocyanide 4-Methylsulphonylacetophenone 1-Methyl-4-(methylsulfonyl)-benzene 4-TOLUENESULFONYLACETONE 2-(ethylsulfonyl)-5-(trifluoromethyl)aniline N-AMINO-2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE METHYLTHIOMETHYL P-TOLYL SULFONE Tosyl cyanide 2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE
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