THIONAZIN

THIONAZIN Basic information
Product Name:THIONAZIN
Synonyms:o,o-diethylo-pyrazinylphosphorothioate;o,o-diethylo-pyrazinylthiophosphate;zinophos4-eemulsifiableconcentrate;Zynophos;CYNEM(R);Ethyl pyrazinyl phosphorothioate;NAMAFOS(R);O, O-DIETHYL O-(2-PYRAZINYL) PHOSPHOROTHIOATE
CAS:297-97-2
MF:C8H13N2O3PS
MW:248.24
EINECS:206-049-6
Product Categories:
Mol File:297-97-2.mol
THIONAZIN Structure
THIONAZIN Chemical Properties
Melting point -1.7℃
Boiling point bp 80°
density 1.204-1.210 g/cm3 (25 ºC)
refractive index 1.5131 (589.3 nm 25℃)
Fp 100 °C
storage temp. 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly)
form liquid
pka-1.22±0.10(Predicted)
Water Solubility 1.14g/L(25 ºC)
BRN 884916
Stability:Hygroscopic
EPA Substance Registry SystemThionazin (297-97-2)
Safety Information
Hazard Codes T+,Xn,F
Risk Statements 27/28-40-21/22-36-20/21/22-11
Safety Statements 36/37/39-38-45-36/37-26-16
RIDADR 3018
WGK Germany 2
RTECS TF5775000
HazardClass 6.1(a)
PackingGroup I
HS Code 29339900
Hazardous Substances Data297-97-2(Hazardous Substances Data)
ToxicityLD50 in female, male rats (mg/kg): 3.5, 6.4 orally; 11, 17 dermally (Gaines)
MSDS Information
THIONAZIN Usage And Synthesis
Chemical PropertiesAmber liquid. Slightly soluble in water; miscible with most organic solvents.
UsesNematocide; insecticide.
DefinitionChEBI: Thionazin is an organic thiophosphate.
General DescriptionAmber liquid. Pure compound is almost colorless; technical product is light brown to tan. Used in insecticides, fungicides, and nematocides. Not registered as a pesticide in the U.S.
Reactivity ProfileOrganothiophosphates, such as THIONAZIN, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
HazardToxic by ingestion, inhalation, and skin absorption; cholinesterase inhibitor.
Health HazardExtremely toxic by ingestion and skinabsorption; cholinesterase inhibitor; exhibitsacute, delayed, and chronic effect; symptomsof cholinergic effects include excessive salivation, lacrimation, blurred vision, musclespasms, headache, weakness, mental confusion, vomiting, diarrhea, stomach pain, convulsions, and coma; also causes shortnessof breath, respiratory depression, and respiratory paralysis; ingestion of small quantity(0.5–1.59) could be fatal to adult humans;poisoning effects may onset several hoursafter exposure.
LD50 oral (rat): 3.5–6 mg/kg
LD50 oral (mouse): 5 mg/kg
LD50 skin (rat): 8 mg/kg
LD50 skin (guinea pig): 10 mg/kg.
Health HazardCholinesterase inhibitor. (Non-Specific -- Organic Phosphate Compound, Liquid, Poison B). Poisonous; may be fatal if inhaled, swallowed or absorbed through skin. Contact may cause burns to skin and eyes.
Fire Hazard(Non-Specific -- Organic Phosphate Compound, Liquid, Poison B). THIONAZIN may burn but does not ignite readily. (Non-Specific -- Organic Phosphate Compound, Liquid, Poison B). Fire may produce irritating or poisonous gases.
Safety ProfilePoison by ingestion, skin contact, and ocular routes. A cholinesterase inhibitor type of insecticide. When heated to decomposition it emits highly toxic fumes of NOx, POx, and SOx. See also PARATHION.
THIONAZIN Preparation Products And Raw materials
THIONAZIN 100 NG/5L IN ACETONITRIL PES THIONAZIN, 1X1ML, METHYLENE CHLORIDE, 2000UG/ML THIONAZIN Thionazin-d10 THIONAZIN OXYGEN ANALOG),thionazin oxygen analogue,THIONAZIN-O-ANALOG,THIONAZIN-O-ANALOGUE,THIONAZIN-OXON THIONAZIN, 1X1ML, METHYLENE CHLORIDE, 20 00UG/ML THIONAZIN-O-ANALOG 100MG [R] Quinalphos

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