ChemicalBook Product Catalog Chemical Reagents Organic reagents fatty acid (R)-(+)-2-BROMOPROPIONIC ACID

(R)-(+)-2-BROMOPROPIONIC ACID

(R)-(+)-2-BROMOPROPIONIC ACID Basic information
Product Name:(R)-(+)-2-BROMOPROPIONIC ACID
Synonyms:PROPANOIC ACID, 2-BROMO-, (2R)-;(R)-(+)-2-BROMOPROPIONIC ACID;2-R-(+) bromopropionic acid;(R)-(+)-2-Bromopropionic acid, GC 98%;(R)-(+)-2-BROMOPROPIONIC ACID 98+%;(R)-(+)-2-Bromopropionic acid, >85% ee, 99%;(R)-(+)-2-Bromopropionic acid, 99%, ee:>85%;(R)-2-Bromopropanoic acid
CAS:10009-70-8
MF:C3H5BrO2
MW:152.97
EINECS:
Product Categories:Organic Building Blocks;Carboxylic Acids (Chiral);Chiral Building Blocks;Synthetic Organic Chemistry;Carboxylic Acids;Chiral Building Blocks
Mol File:10009-70-8.mol
(R)-(+)-2-BROMOPROPIONIC ACID Structure
(R)-(+)-2-BROMOPROPIONIC ACID Chemical Properties
Melting point 25°C
Boiling point 203 °C
density 1.692 g/mL at 20 °C (lit.)
refractive index n20/D 1.475
Fp 100 °C
storage temp. 2-8°C
pka3.00±0.10(Predicted)
form clear liquid
color Colorless to Brown
optical activity[α]20/D +26±2°, neat
BRN 1720262
Safety Information
Hazard Codes C
Risk Statements 22-34
Safety Statements 26-36/37/39-45
RIDADR UN 3265 8/PG 3
WGK Germany 3
F 10
HazardClass 8
PackingGroup III
HS Code 29159000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
(R)-(+)-2-BROMOPROPIONIC ACID Usage And Synthesis
Chemical Propertiesclear colorless to light brown liquid
Purification MethodsDissolve it in Et2O, dry (CaCl2), evaporate and distil it through a short column. Distillation through a Podbielniak column (p 11) (see S-(-)-2-chloropropionic acid below) led to decomposition. Store it in the dark under N2, preferably in sealed ampoules. Even at -10o it slowly decomposes. [Fuet et al. J Am Chem Soc 76 6054 1954, Beilstein 2 IV 761.]
(R)-(+)-2-BROMOPROPIONIC ACID Preparation Products And Raw materials
Raw materials[R,(+)]-2-Bromopropanoic acid methyl ester-->(S)-2-((Methylsulfonyl)oxy)propanoic acid-->L-Alanine-->Cinchonine-->2-Bromopropionic acid-->D-Alanine
Preparation Products(S)-(-)-2-BROMOPROPIONIC ACID
2-Methyl-2-bromopropionic acid methyl ester 1-BROMO-CYCLOBUTANECARBOXYLIC ACID ETHYL ESTER 2-Methyl-2-bromopropionic acid Diethyl 2,5-dibromohexanedioate METHYL 1-BROMOCYCLOHEXANECARBOXYLATE Diethyl 2-bromo-2-methylmalonate 1-BROMO-CYCLOHEXANECARBOXYLIC ACID ETHYL ESTER ethyl 2-bromo-2-ethylbutanoate 2-BROMODIETHYLACETIC ACID Ethyl 2-bromoisobutyrate DIMETHYL BROMOMALONATE Isopropyl 2-bromo-2-methylpropanoate 2-BROMOISOBUTYRIC ACID N-BUTYL ESTER 5-BROMO-2.2.5-TRIMETHYL-1.3-DIOXANE-4.6-DIONE DIETHYL DIBROMOMALONATE DIETHYL BROMOMALONATE DIMETHYL DIBROMOMALONATE meso-2,3-Dibromosuccinic acid
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