(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide

(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Basic information
Product Name:(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide
Synonyms:1-FLUORO-2,4-DINITROPHENYL-5-L-ALANINE AMIDE;Nα-(2,4-Dinitro-5-fluorophenyl)-L-alanine amide≥ 98% (HPLC);NALPHA-(5-FLUORO-2,4-DINITROPHENYL)-L-ALANINAMIDE;N-ALPHA-(2,4-DINITRO-5-FLUOROPHENYL)-L-ALANINAMIDE;N-ALPHA-(2,4-DINITRO-5-FLUOROPHENYL)-L-ALANINE AMIDE;(2,4-Dinitro-5-fluorophenyl) L-Alaninamide;Marfey's Reagent, 99%, for chiral derivatization;Nalpha-(5-Fluoro-2,4-dinitrophenyl)-L-alaninamide [HPLC Labeling Reagent for e.e. Determination]
CAS:95713-52-3
MF:C9H9FN4O5
MW:272.19
EINECS:
Product Categories:proteinmod;Amino Acids & Derivatives;Aromatics;Chiral Reagents;Intermediates & Fine Chemicals;Pharmaceuticals;Amino Group Labeling Reagents for HPLC;Analytical Chemistry;e.e. Determination (HPLC Labeling Reagents);Enantiomer Excess & Absolute Configuration Determination;HPLC Labeling Reagents;UV Detection (HPLC Labeling Reagents)
Mol File:95713-52-3.mol
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Structure
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Chemical Properties
Melting point 229 °C
Boiling point 544.5±50.0 °C(Predicted)
density 1.592±0.06 g/cm3(Predicted)
storage temp. 2-8°C
solubility acetone: 10 mg/mL, clear, yellow
form powder
pka15.61±0.50(Predicted)
color yellow to orange
optical activity[α]20/D +56±2°, c = 1% in acetone
BRN 6820069
InChIKeyNEPLBHLFDJOJGP-BYPYZUCNSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29242990
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Usage And Synthesis
Chemical PropertiesLight yellow to yellow crystal or powder
UsesFDAA was used as derivatizing reagent, in a study performed to understand unusual amino acids using reversed phase high performance liquid chromatography-electrospray ionization mass spectrometry (RPHPLC-ESI-MS).
Uses(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide can be used for chiral amino acid analysis.
UsesN-α-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide is suitable for use for the derivatization of amino acids. glutamate and analine present in cell wall. Derivatized?D- and?L-amino acids can be resolved and quantitated by HPLC.
General DescriptionNα-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide (FDAA) is a chiral derivatizing agent (CDA), has high enantioselectivity but low sensitivity as compared to other CDAs. It is generally used to assign the stereochemistry of amino acids in trace amounts.
Biochem/physiol ActionsN-α-(2,4-Dinitro-5-fluorophenyl)-L-alaninamide (FDAA) is a chiral derivatizing agent and is used routinely to improve the detection of underivatized amino acids in high performance liquid chromatography. Its usage is effective in separating stereoisomer.
(S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide Preparation Products And Raw materials
3-FLUORO-N-METHYLANILINE FDNP-VAL-NH2 2,4-DINITRO-5-FLUOROANILINE 2,4-DIAMINOFLUOROBENZENE N1-(2,4-DINITRO-PHENYL)-ETHANE-1,2-DIAMINE N-Isopropyl-3-fluoroaniline N-(2-AMINO-ETHYL)-BENZENE-1,2-DIAMINE 5-Fluoro-2-nitroaniline (S)-2-(5-fluoro-2,4-dinitrophenylaMino)propanaMide (3-fluoro-4-nitrophenyl)methanamine 2-FLUORO-BENZENE-1,4-DIAMINE 3,4-Diaminofluorobenzene 4-FLUORO-2-NITROANILINE 2-Fluoro-5-nitroaniline 4-FLUORO-5-NITROBENZENE-1,2-DIAMINE 2,4-Dinitrofluorobenzene 3-Fluoro-4-nitroaniline N-(2-NITRO-PHENYL)-ETHANE-1,2-DIAMINE

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