3-Methyl-1-phenyl-2-phospholene 1-oxide

3-Methyl-1-phenyl-2-phospholene 1-oxide Basic information
Product Name:3-Methyl-1-phenyl-2-phospholene 1-oxide
Synonyms:3-methyl-1-phenyl-2-phospholen1-oxide;3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE;3-METHYL-1-PHENYL-2-PHOSPHOLENE OXIDE;4-METHYL-1-PHENYL-2,3-DIHYDRO-1H-1LAMBDA5-PHOSPHOL-1-ONE;4-METHYL-1-PHENYL-2,3-DIHYDROPHOSPHOL-1-ONE;2,3-DIHYDRO-4-METHYL-1-PHENYL-1H-PHOSPHOLE 1-OXIDE;3-Methyl-1-Phenyl-2-Phosphelene 1-Oxide;3-METHYL-1-PHENYL-2-PHOSPHOLENE 1-OXIDE TECH., 85%
CAS:707-61-9
MF:C11H13OP
MW:192.19
EINECS:211-901-5
Product Categories:Catalysis and Inorganic Chemistry;Phosphorus Compounds;Phosphorus Precursors;707-61-9
Mol File:707-61-9.mol
3-Methyl-1-phenyl-2-phospholene 1-oxide Structure
3-Methyl-1-phenyl-2-phospholene 1-oxide Chemical Properties
Melting point 58-62 °C
Boiling point 150 °C/0.15 mmHg (lit.)
density 1.11±0.1 g/cm3(Predicted)
refractive index n20/D 1.5707(lit.)
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Soluble in polar solvents.
form Lumps
color White to cream
Sensitive Hygroscopic
BRN 609223
CAS DataBase Reference707-61-9(CAS DataBase Reference)
EPA Substance Registry System1H-Phosphole, 2,3-dihydro-4-methyl-1-phenyl-, 1-oxide (707-61-9)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38-40
Safety Statements 26-28-36/37/39-45
WGK Germany 3
RTECS SZ6105100
TSCA Yes
HS Code 2931499090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
3-Methyl-1-phenyl-2-phospholene 1-oxide Usage And Synthesis
Chemical Propertieswhite to yellow adhering crystals
Uses3-Methyl-1-phenyl-2-phospholene 1-oxide is used as a catalyst for intramolecular aza-wittig cyclization reactions and polymerization reactions. It is a reactant used for the preparation of phospha sugars and their radical bromination derivatives as anticancer agents.
ApplicationCatalyst for:
Intramolecular aza-Wittig cyclization reactions
Polymerization reactions
Reactant for preparation of:
Phospha sugars and their radical bromination derivatives as anticancer agents
(METHYL-VINYL-PHOSPHINOYL)-BENZENE 3-Methyl-1-phenyl-2-phospholene 1-oxide 3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE,3-METHYL-1-PHENYL-3-PHOSPHOLENE 1-OXIDE (=3-METHYL-1-PHENYL-1-PHOSPHA-3-CYCLOPENTENE 1-OXIDE) 95+% TRIMETHYLPHOSPHINE OXIDE (ETHYL-VINYL-PHOSPHINOYL)-BENZENE

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