Citronellyl tiglate

Citronellyl tiglate Basic information
Product Name:Citronellyl tiglate
Synonyms:2-Butenoic acid, 2-methyl-, 3,7-dimethyl-6-octenyl ester, (E)-;2-methyl-,3,7-dimethyl-6-octenylester,(e)-2-butenoicaci;2-methyl-,3,7-dimethyl-6-octenylester,(E)-2-Butenoicacid;3,7-Dimethyl-6-octenyl (2Z)-2-methyl-2-butenoate;E-Citronellyl tiglate;CITRONELLYL TIGLATE;CITRONELLYL-CROTONATE;3,7-dimethyl-6-octenyl 2-methylcrotonate
CAS:24717-85-9
MF:C15H26O2
MW:238.37
EINECS:246-426-2
Product Categories:Alphabetical Listings;C-D;Flavors and Fragrances
Mol File:24717-85-9.mol
Citronellyl tiglate Structure
Citronellyl tiglate Chemical Properties
Boiling point 144-145 °C9 mm Hg(lit.)
density 0.903 g/mL at 25 °C(lit.)
vapor pressure 1.4Pa at 25℃
refractive index n20/D 1.465(lit.)
FEMA 4295 | CITRONELLYL TRANS-2-METHYL-2-BUTENOATE
Fp >230 °F
color A colourless or pale straw-coloured liquid.
Odorat 100.00 %. rose fruity floral geranium leafy tea
Odor Typefloral
Water Solubility 385μg/L at 20℃
JECFA Number1823
LogP5.99 at 25℃
NIST Chemistry ReferenceCitronellyl tiglate(24717-85-9)
EPA Substance Registry System2-Butenoic acid, 2-methyl-, 3,7-dimethyl-6-octenyl ester, (2E)- (24717-85-9)
Safety Information
WGK Germany 2
toxicityBoth the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1975).
MSDS Information
ProviderLanguage
SigmaAldrich English
Citronellyl tiglate Usage And Synthesis
Chemical PropertiesCitronellyl Tiglate is a liquid with a floral, rosy, fruity, mushroomlike odor. It is used in geranium oil reconstitutions.
Chemical PropertiesColorless liquid; winey rosy aroma.
OccurrenceReported found in geranium petiole oil India (3.93%), geranium stem oil India (1.88%), geranium leaf oil Rwanda (0.14%) and geranium leaf oil India (1.40%).
PreparationBy direct esterification of citronellol with 2-butenoic acid under azeotropic conditions (Arctander. 1969).
Aroma threshold valuesMedium strength odor, floral type.
Citronellyl tiglate Preparation Products And Raw materials
Xylene GLYCERYL MONOSTEARATE N,N-Dimethylformamide Alginic Sodium Diester Monostearin Poly(dimethylsiloxane) Tiglic acid ETHANE Citronellyl tiglate Citronella grass oil PartialFattyAcidEsterofGlycerine N,N-Dimethylallylamine Dimethyl sulfoxide Dimethyl ether Dimethyl carbonate AcidEster Dimethyl phthalate Dimethyl sulfate

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