ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Acyclic hydrocarbons CIS-3-HEXENE

CIS-3-HEXENE

CIS-3-HEXENE Basic information
Product Name:CIS-3-HEXENE
Synonyms:(3Z)-3-Hexene;(Z)-3-C6H12;(Z)-3-Hexene;CIS-3-HEXENE;3-hexene,(Z)-;cis-hex-3-ene;cis-3-hexene93+%;cis-3-Hexene, pure, 97%
CAS:7642-09-3
MF:C6H12
MW:84.16
EINECS:
Product Categories:Acyclic;Alkenes;Organic Building Blocks
Mol File:7642-09-3.mol
CIS-3-HEXENE Structure
CIS-3-HEXENE Chemical Properties
Melting point -137.82°C
Boiling point 67 °C
density 0.677
refractive index 1.3935-1.3955
Fp -12 °C
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.677
BRN 1718858
LogP3.420 (est)
EPA Substance Registry System3-Hexene, (3Z)- (7642-09-3)
Safety Information
Hazard Codes Xn-F,Xn,F
Risk Statements 65-11-36
Safety Statements 62-16-26
RIDADR 3295
WGK Germany 3
HazardClass 3
PackingGroup II
HS Code 29012990
MSDS Information
ProviderLanguage
ACROS English
CIS-3-HEXENE Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
Usescis-3-Hexene is used as an organic chemical synthesis intermediate.
DefinitionChEBI: Cis-3-hexene is a 3-hexene in which the double bond adopts a cis-configuration.
General Descriptioncis-3-Hexene is a symmetrical cis-disubstituted alkene that can be prepared by the hydroboration of 3-hexyne followed by protonolysis. The gas-phase study of its molecular structure by electron diffraction combined with molecular mechanical calculations reveals the presence of the (+ac, +ac) and the (-ac, +ac) forms. cis-3-Hexene undergoes epoxidation with dimethyldioxirane to form the corresponding epoxide.
CIS-3-HEXENE Preparation Products And Raw materials
Raw materialsPhosphorane, triphenylpropylidene--->TRANS-3-HEXENE-->CIS-2-HEXENE
Preparation ProductsCIS-3-HEXENYL BUTYRATE-->FEMA 3498-->cis-3-Hexenai-->3-Hexanol-->TRANS-3-HEPTENE-->2-ETHYL-1-BUTENE
Jasmone 1,4,5,8,9,10-Hexahydroanthracene 2-CYCLOPENTENE-1-ACETIC ACID 1,2,3,4,5,6-HEXAMETHYLBICYCLO[2.2.0]HEXA-2,5-DIENE (-)-MYRTENOL 2,5-Dimethyl-3,4-diphenylcyclopentadienone (1R)-(+)-ALPHA-PINENE Cyclohexa-1,4-diene ALPHA-PINENE Colchicine 2-CARENE cis-VERBENOL 3-CARENE (-)-VERBENONE 1,2,3,4-TETRAPHENYL-1,3-CYCLOPENTADIENE 1,2,3,4,5-Pentamethylcyclopentadiene Tetraphenylcyclopentadienone 1-METHYL-1,4-CYCLOHEXADIENE
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