ChemicalBook Product Catalog Chemical Reagents Organic reagents Cyanide / nitrile 2-METHYLGLUTARONITRILE

2-METHYLGLUTARONITRILE

2-METHYLGLUTARONITRILE Basic information
Product Name:2-METHYLGLUTARONITRILE
Synonyms:2-METHYLGLUTARONITRILE;1,3-DICYANOBUTANE;METHYLGLUTARONITRILE;1,5-Valerodinitrile, 2-methyl-;2,4-Dicyanobutane;2-Methyl glutarodinitrile;2-Methyl pentanedinitrile;2-methyl-1,5-valerodinitrile
CAS:4553-62-2
MF:C6H8N2
MW:108.14
EINECS:224-923-5
Product Categories:C6 to C7;Cyanides/Nitriles;Nitrogen Compounds
Mol File:4553-62-2.mol
2-METHYLGLUTARONITRILE Structure
2-METHYLGLUTARONITRILE Chemical Properties
Melting point −45 °C(lit.)
Boiling point 269-271 °C(lit.)
density 0.95 g/mL at 25 °C(lit.)
vapor pressure 1.9Pa at 20℃
refractive index n20/D 1.434(lit.)
Fp >230 °F
storage temp. Store at +2°C to +8°C.
solubility water: soluble
form clear liquid
color Colorless to Light yellow to Light orange
explosive limit0.3-3.25%(V)
Water Solubility 52.3g/L at 20℃
BRN 1741955
InChIKeyFPPLREPCQJZDAQ-UHFFFAOYSA-N
LogP0.46 at 20℃
CAS DataBase Reference4553-62-2(CAS DataBase Reference)
EPA Substance Registry System2-Methylglutaronitrile (4553-62-2)
Safety Information
Hazard Codes Xn,T
Risk Statements 20/21/22-23/25-21
Safety Statements 36/37-45-36/37/39
RIDADR 3276
WGK Germany 3
RTECS YV8140000
HS Code 2926.90.5050
HazardClass 6.1(b)
PackingGroup III
Hazardous Substances Data4553-62-2(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
2-METHYLGLUTARONITRILE Usage And Synthesis
Uses2-Methylglutaronitrile (MGN) may be used in the synthesis of 1,5-dimethyl-2-piperidone (1,5-DMPD) by chemoenzymatic process.
General DescriptionAmber liquid.
Air & Water ReactionsWater soluble.
Reactivity ProfileNitriles, such as 2-METHYLGLUTARONITRILE, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.
Health HazardACUTE/CHRONIC HAZARDS: 2-METHYLGLUTARONITRILE is readily absorbed through the skin.
Fire Hazard2-METHYLGLUTARONITRILE is combustible.
2-METHYLGLUTARONITRILE Preparation Products And Raw materials
Raw materials3-CYANOPROPIONALDEHYDE DIMETHYL ACETAL-->Methanol-->carbon monoxide-->Propionitrile-->Acrylonitrile
Preparation Products5-METHYL-2-PIPERIDINONE-->2,5,6-trichloronicotinaMide
CCG 2046 2-(4-BENZOYLPHENYL)-2-PHENYLPENTANEDINITRILE SALOR-INT L153214-1EA SALOR-INT L153206-1EA 2,4-DICYANO-3-ETHYL-3-METHYLGLUTARIMIDE 2,4-DICYANO-3-METHYLGLUTARAMIDE 1,1,3,3-PROPANETETRACARBONITRILE SALOR-INT L153257-1EA 2-METHYLGLUTARONITRILE RARECHEM AQ C6 0011 6-MERCAPTO-4,4-DIMETHYL-2-OXO-1,2,3,4-TETRAHYDROPYRIDINE-3,5-DICARBONITRILE SALOR-INT L153249-1EA 1,3,6-HEXANETRICARBONITRILE 2-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-2-(4-METHOXYPHENYL)PENTANEDINITRILE 2-(2-AMINO-6-CHLORO-3-CYANO-4H-CHROMEN-4-YL)MALONONITRILE SALOR-INT L153281-1EA DBDCB SALOR-INT L153192-1EA
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