Silver benzoate

Silver benzoate Basic information
Product Name:Silver benzoate
Synonyms:Benzoic acid silver(I) salt;Silver benzoate,99%;Silver benzoate ,98.5%;Silver benzoate, 99% 10GR;Silver benzoate, 99% 50GR;Silver benzoate hydrate,98% AgC6H5COO;Silver benzoate 99%;Silver benzoate hydrate
CAS:532-31-0
MF:C7H6AgO2
MW:229.99
EINECS:208-533-2
Product Categories:Ag;Carboxylic Acid SaltsMicro/Nanoelectronics;Carbonyl Compounds;Organic Building Blocks;Silver;Solution Deposition Precursors
Mol File:532-31-0.mol
Silver benzoate Structure
Silver benzoate Chemical Properties
Melting point >188°C (dec.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility cold water: soluble385 part(lit.)
form Powder
color White to cream or gray
Water Solubility Insoluble in water.
Sensitive Light Sensitive
InChIKeyCLDWGXZGFUNWKB-UHFFFAOYSA-M
CAS DataBase Reference532-31-0(CAS DataBase Reference)
EPA Substance Registry SystemBenzoic acid, silver(1+) salt (532-31-0)
Safety Information
Safety Statements 24/25
WGK Germany 3
TSCA Yes
HS Code 28432900
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Silver benzoate Usage And Synthesis
Chemical PropertiesOff-White Crystalline Powder
UsesSilver benzoate is an aromatic salt that is used as a catalyst to prepare β-amino acids (such as N-Acetyl-β-alanine) from α-amino acids (such as D-Alanine). Silver benzoate is also used as a catalyst in Wolff rearrangement reactions.
ApplicationSilver benzoate was used in the synthesis of triphenyltinbenzoate. It is an efficient catalytic system for the reaction of carbon dioxide with various ketones.
ReactionsSilver benzoate reacts with bromine in CCl4 refluxing to form C6H5Br This reaction is called Hunsdiecker reaction.
General DescriptionSilver benzoate along with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) is an efficient catalytic system for the reaction of carbon dioxide with various ketones.
SynthesisSilver benzoate can be obtained by reacting silver nitrate and sodium benzoate:
AgNO3 + PhCOONa → PhCOOAg↓ + NaNO3
Reaction: Mix an equimolar amount of silver nitrate solution with sodium benzoate solution to precipitate silver benzoate. Washed with water and dried in a vacuum desiccator.
Silver benzoate Preparation Products And Raw materials
Raw materialsSilver nitrate-->Sodium benzoate
ZINC BENZOATE Silver benzoate SILVER SALICYLATE Silver

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