ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic ketones 2'-Fluoroacetophenone

2'-Fluoroacetophenone

2'-Fluoroacetophenone Basic information
Product Name:2'-Fluoroacetophenone
Synonyms:Fluoroacetophenone1;Fluoroacetophenonemincolorlessliq;1-(2-FLUOROPHENYL)ETHANONE;2'-FLUOROACETOPHENONE;2-FLUOROACETOPHENONE;Ethanone, 1-(2-fluorophenyl)-;O-FLUOROACETOPHENONE;LABOTEST-BB LT01148268
CAS:445-27-2
MF:C8H7FO
MW:138.14
EINECS:207-156-0
Product Categories:Aromatic Acetophenones & Derivatives (substituted);Fluorobenzene;ketone;Adehydes, Acetals & Ketones;Fluorine Compounds;C7 to C8;Acetophenone Series;Aryl Fluorinated Building Blocks;Building Blocks;C7 to C8;C8-C12;Carbonyl Compounds;Chemical Synthesis;Fluorinated Building Blocks;Carbonyl Compounds;Ketones;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;11;445-27-2;pharmaceutical
Mol File:445-27-2.mol
2'-Fluoroacetophenone Structure
2'-Fluoroacetophenone Chemical Properties
Melting point 26-27C
Boiling point 187-189 °C(lit.)
density 1.137 g/mL at 20 °C(lit.)
refractive index n20/D 1.507(lit.)
Fp 143 °F
storage temp. Sealed in dry,Room Temperature
solubility Soluble in Acetone, Chloroform, Dichloromethane, Ethanol, Ethyl Acetate and Methanol.
form Liquid
Specific Gravity1.121
color Clear colorless to yellow
BRN 2041344
InChIKeyQMATYTFXDIWACW-UHFFFAOYSA-N
CAS DataBase Reference445-27-2(CAS DataBase Reference)
NIST Chemistry Referenceo-Fluoroacetophenone(445-27-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39-37
RIDADR 1993
WGK Germany 3
HazardClass IRRITANT
PackingGroup III
HS Code 29147090
MSDS Information
ProviderLanguage
1-(2-Fluorophenyl)ethanone English
SigmaAldrich English
ACROS English
ALFA English
2'-Fluoroacetophenone Usage And Synthesis
Chemical Propertiesclear colorless to light yellow or light green
Uses2'-Fluoroacetophenone is used as starting reagent in the synthesis of ascididemin. It is used to produce 1-(2-piperidin-1-yl-phenyl)-ethanone by reaction with piperidine.
Synthesis Reference(s)Tetrahedron Letters, 31, p. 6179, 1990 DOI: 10.1016/S0040-4039(00)97018-7
General DescriptionThe enantioselective reduction of 2′-fluoroacetophenone has been investigated.
2'-Fluoroacetophenone Preparation Products And Raw materials
Preparation Products5-Fluoro-1-tetralone-->5-(2-fluorophenyl)-1H-pyrrole-3-carbonitrile-->ethyl 2-amino-4-(2-fluorophenyl)thiophene-3-carboxylate-->N-[1-(2-Fluorophenyl)ethylidene]-4-methylbenzenesulfonamide-->5-bromo-2-(2-fluorophenyl)-1H-indole-->N-Boc-3-Methyl-5-nitroindazole-->Ethanone, 1-(2-fluorophenyl)-2-(methylthio)--->1-(2-Fluorophenyl)ethanamine hydrochloride-->2'-(1-Piperidinyl)acetophenone
2-Fluorophenylacetic acid 4'-Bromoacetophenone 2,4'-Difluorobenzophenone 3-Aminoacetophenone 2-Fluorobenzyl cyanide 2',4'-Difluoroacetophenone 3'-Fluoroacetophenone ,97% 2'-Fluoroacetophenone Acetophenone 2',4'-Dichloroacetophenone L-PICEIN 2-Bromoacetophenone 4-Fluoroacetophenone 4'-Hydroxyacetophenone 2'-FLUOROPROPIOPHENONE 3-(2-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER 2'-Hydroxyacetophenone 4'-(Trifluoromethyl)acetophenone
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