Phenyl 2-pyridyl ketoxime

Phenyl 2-pyridyl ketoxime Basic information
Product Name:Phenyl 2-pyridyl ketoxime
Synonyms:2-BENZOYLPYRIDINE KETOXIME;2-Benzoylpyridine oxime;2-Benzoylpyridiineketoxime;PPKO;PHENYL-ALPHA-PYRIDYL KETOXIME;PHENYL-A-PYRIDYL KETOXIME;PHENYL 2-PYRIDYL KETONE OXIME;PHENYL 2-PYRIDYL KETOXIME
CAS:1826-28-4
MF:C12H10N2O
MW:198.22
EINECS:217-374-8
Product Categories:Heterocyclic Compounds;Analytical Chemistry;Bipyridyls, etc. (Chelating Reagents);Chelating Reagents;C9 to C46;Heterocyclic Building Blocks;Pyridines
Mol File:1826-28-4.mol
Phenyl 2-pyridyl ketoxime Structure
Phenyl 2-pyridyl ketoxime Chemical Properties
Melting point 154-156 °C (lit.)
storage temp. Store below +30°C.
form Crystalline Powder
color Slightly pink
Water Solubility insoluble
CAS DataBase Reference1826-28-4(CAS DataBase Reference)
NIST Chemistry ReferencePhenyl-«alpha»-pyridyl ketoxime(1826-28-4)
EPA Substance Registry SystemMethanone, phenyl-2-pyridinyl-, oxime (1826-28-4)
Safety Information
Hazard Codes T,Xi
Risk Statements 25-37/38-41-36/37/38
Safety Statements 26-36/37/39-45-37/39
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
TSCA Yes
HazardClass 6.1
HS Code 29333990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Phenyl 2-pyridyl ketoxime Usage And Synthesis
Chemical PropertiesSlightly pinl crystalline powder
UsesPhenyl 2-pyridyl ketoxime was used in preparation of inverse-9-metallacrown-3, trinuclear clusters.
General DescriptionThe complexation reaction of phenyl 2-pyridyl ketoxime with some transition and heavy metal ions Co2+, Ni2+, Zn2+, Pb2+, Fe2+, Fe3+, Cr3+ and La2+ has been studied potentiometrically. The reactions of phenyl(2-pyridyl)ketone oxime, with nickel(II) sulfate hexahydrate, in the absence of an external base, have been investigated.
Purification MethodsThe E-isomer crystallises from EtOH (charcoal). It isomerizes to the Z-isomer on melting or in boiling o-xylene, and crystallises from EtOH or cyclohexanol with m 166-168o. [Beilstein 21 H 330, 21 III/IV 4120, 21/8 V 568.]
Phenyl 2-pyridyl ketoxime Preparation Products And Raw materials
[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL](2,4-DICHLOROPHENYL)METHANONE OXIME Copper Pyrithione 3-CHLORO-2-[(([(4-METHOXYANILINO)CARBONYL]OXY)IMINO)(PHENYL)METHYL]-5-(TRIFLUOROMETHYL)PYRIDINE PHENYL RESIN Phenylacetone [3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL](PHENYL)METHANONE OXIME Diphenyl ether Phenyl 2-pyridyl ketoxime PHENYL VALERATE Zinc pyrithione [3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL](4-METHOXYPHENYL)METHANONE OXIME PHENYL 2-PYRIDYL KETOXIME, (2-BENZOYLPYRIDINE KETOXIME) Acetone oxime (4-CHLOROPHENYL)[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]METHANONE OXIME 3-CHLORO-2-[(([(2,4-DICHLOROANILINO)CARBONYL]OXY)IMINO)(PHENYL)METHYL]-5-(TRIFLUOROMETHYL)PYRIDINE 1-Isoquinolinylphenylmethanoneoxime Phenylacetic acid 2-Benzoylpyridine

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