ChemicalBook Product Catalog Chemical Reagents Organic reagents Boric acid 4-(Hydroxymethyl)phenylboronic acid

4-(Hydroxymethyl)phenylboronic acid

4-(Hydroxymethyl)phenylboronic acid Basic information
Product Name:4-(Hydroxymethyl)phenylboronic acid
Synonyms:α-Hydroxy-p-tolueneboronic acid;(4-methylolphenyl)boronic acid;4-(HydroxyMethyl)phenylboronic acid, 95+%;4-(HYDROXYMETHYL)PHENYLBORONIC ACID;4-(HYDROXYMETHYL)BENZENEBORONIC ACID;(4-Boronophenyl)methanol;AKOS BRN-0115;4-(Hydroxymethyl)Phenylboronic
CAS:59016-93-2
MF:C7H9BO3
MW:151.96
EINECS:
Product Categories:blocks;BoronicAcids;Boronic Acid series;Aryl;Organoborons;B (Classes of Boron Compounds);Substituted Boronic Acids;Boronic acids;Heterocyclic Compounds;Boronic Acid;Boronic Acids;Boronic Acids and Derivatives
Mol File:59016-93-2.mol
4-(Hydroxymethyl)phenylboronic acid Structure
4-(Hydroxymethyl)phenylboronic acid Chemical Properties
Melting point 251-256 °C (lit.)
Boiling point 362.0±44.0 °C(Predicted)
density 1.25±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Crystalline Powder
pka8.53±0.10(Predicted)
color White to slightly yellow
PH4.5 (10g/l, H2O)
Water Solubility 25 g/L
BRN 2831413
InChIKeyPZRPBPMLSSNFOM-UHFFFAOYSA-N
CAS DataBase Reference59016-93-2(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26-36
WGK Germany 3
HazardClass IRRITANT
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
4-(Hydroxymethyl)phenylboronic acid Usage And Synthesis
Chemical PropertiesOff-white Cryst
Usessuzuki reaction
UsesReactant involved in the synthesis of biologically active compounds including:
  • Imidazo[4,5-b]pyrazin-2-ones for use as mTOR kinase inhibitors
  • Human immunodificiency virus protease inhibitors with activity against resistant viruses

Reactant involved in:
  • Suzuki coupling reactions
  • Copper-catalyzed transformation from arylboronic acids in water

Involved in the synthesis of polyurethane containing spindle-type chromophores
4-METHOXYCARBONYL-2-NITROPHENYLBORONIC ACID (4-BENZYLOXYCARBONYL-2-NITRO)BENZENEBORONIC ACID 4-Carboxyphenylboronic acid 4-Ethoxycarbonyl-2-nitrophenylboronic acid (4-BENZYLOXYCARBONYLPHENYL)BORONIC ACID 3,5-DIFLUORO-4-(HYDROXYMETHYL)PHENYLBORONIC ACID methylol cellulose 4-(Acetoxymethyl)benzeneboronic acid pinacol ester 4-CARBOXY-2-NITROPHENYLBORONIC ACID Methyl 2-hydroxyethyl cellulose 3-Ethoxycarbonylphenylboronic acid (2-AMINO-4-METHOXYCARBONYLPHENYL)BORONIC ACID HYDROCHLORIDE 4-(Hydroxymethyl)phenylboronic acid 4-METHOXYCARBONYL-2,6-DIFLUOROPHENYLBORONIC ACID 4-Carboxy-3-fluorophenylboronic acid 2,3-DIFLUORO-4-(5-NONYL-1,3-DIOXAN-2-YL)PHENYLBORONIC ACID CARBOXYMETHYLCELLULOSE SODIUM SALT Tris(hydroxymethyl)aminomethane
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