2-Bromo-2'-nitroacetophenone

2-Bromo-2'-nitroacetophenone Basic information
Product Name:2-Bromo-2'-nitroacetophenone
Synonyms:1-(2-Nitrophenyl)-2-bromoethanone;2'-Nitro-α-bromoacetophenone;2'-NITROPHENACYL BROMIDE;2-BROMO-2'-NITROACETOPHENONE;-Bromo-2'-Nitroacetophenone;2-Bromo-2'-nitroacetophenone,98%;2-Bromo-2'-nitroacetophenone2'-Nitrophenacyl bromide;2-NITROPHENCYL BROMIDE
CAS:6851-99-6
MF:C8H6BrNO3
MW:244.04
EINECS:
Product Categories:Ketone;Carbonyl Compounds;Halides
Mol File:6851-99-6.mol
2-Bromo-2'-nitroacetophenone Structure
2-Bromo-2'-nitroacetophenone Chemical Properties
Melting point 55-57 °C(lit.)
Boiling point 335.7±17.0 °C(Predicted)
density 1.671±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, Methanol
form Crystalline Powder
color White to pale yellow
λmax262nm(EtOH)(lit.)
InChIKeySGXUUCSRVVSMGK-UHFFFAOYSA-N
CAS DataBase Reference6851-99-6(CAS DataBase Reference)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-27-28-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup III
HS Code 29147000
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Bromo-2'-nitroacetophenone Usage And Synthesis
Chemical PropertiesWhite to pale yellow crystalline powder
Uses2-Bromo-2′-nitroacetophenone, an electroactive derivative-forming reagent, was used as a precolumn reagent for preparing prostaglandin derivatives.
Uses2-Bromo-2'-nitroacetophenone is used in the novel synthesis of 5-pyridylindolizine derivatives.
Synthesis Reference(s)Canadian Journal of Chemistry, 61, p. 400, 1983 DOI: 10.1139/v83-072
The Journal of Organic Chemistry, 49, p. 438, 1984 DOI: 10.1021/jo00177a010
2-Bromo-2'-nitroacetophenone Preparation Products And Raw materials
Preparation ProductsN-[2-[3-(1-Piperazinylmethyl)imidazo[2,1-b]thiazol-6-yl]phenyl]-2-quinoxalinecarboxamide-->2-AMINO-1-(2-NITRO-PHENYL)-ETHANONE HYDROCHLORIDE
2-BROMO-1-(4,5-DIMETHOXY-2-NITRO-PHENYL)ETHANONE α-Bromo-4-nitroacetophenone hexamine,A-BROMO-4-NITROACETOPHENONE HEXAMINE 2,3-DIBROMO-3-(3,4-DICHLOROPHENYL)-1-(2-NITROPHENYL)PROPAN-1-ONE 3-Nitrophenacylbromide 2'-Bromo-α-nitroacetophenone 2,3-DIBROMO-1-(2-NITROPHENYL)-3-(3,4,5-TRIMETHOXYPHENYL)PROPAN-1-ONE 3-Nitroacetophenone 4-Nitroacetophenone 3'-Bromo-4'-nitroacetophenone 2',4'-Dichloroacetophenone 2-Bromoacetophenone 2,3-DIBROMO-3-(4-ETHOXY-3-METHOXYPHENYL)-1-(2-NITROPHENYL)PROPAN-1-ONE 2,3-DIBROMO-5-NITRO-1,4-NAPHTHOQUINONE 2-Fluoro-3-Bromio-5-Nitro acetophenone 5'-Bromo-2'-nitroacetophenone Α-BROMO-P-NITROACETOPHENONE 2-BROMO-5-NITROACETOPHENONE 2-Nitroacetophenone

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