ChemicalBook Product Catalog Pharmaceutical intermediates Heterocyclic compound Pyridine compound Bromopyridine Ethyl 6-bromopicolinate

Ethyl 6-bromopicolinate

Ethyl 6-bromopicolinate Basic information
Product Name:Ethyl 6-bromopicolinate
Synonyms:Ethyl 6-bromopicolinate, 2-Bromo-6-(ethoxycarbonyl)pyridine;ETHYL 6-BROMOPYRIDINE-2-CARBOXYLATE;ETHYL-6-BROMO-2-PYRIDINECARBOXYLATE;6-BROMOPYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER;6-BROMOPYRIDINE-2-ETHYL CARBOXYLATE;RARECHEM AL BI 0899;Ethyl 6-bromo-2-piperidinecarboxylate;ETHYL 6-BROMOPICOLINATE
CAS:21190-88-5
MF:C8H8BrNO2
MW:230.06
EINECS:673-818-4
Product Categories:blocks;Bromides;Pyridines;Pyridine;Pyridine Series;Heterocycle-Pyridine series
Mol File:21190-88-5.mol
Ethyl 6-bromopicolinate Structure
Ethyl 6-bromopicolinate Chemical Properties
Melting point 41-42°C
Boiling point 302.7±22.0 °C(Predicted)
density 1.501±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka-0.89±0.10(Predicted)
form solid
color Off-white
CAS DataBase Reference21190-88-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36
Safety Statements 26
HS Code 2933399990
MSDS Information
Ethyl 6-bromopicolinate Usage And Synthesis
Usesethyl 6-bromopicolinate is a model compound for the preliminary screening of dimerization reaction.
PreparationEthyl 6-bromopicolinate was prepared by monolithiation of 2,6-dibromopyridine followed by a reaction with ethyl formate and subsequently by a reaction with iodine in ethanol (Scheme 57). This three-step procedure furnished the required ethyl 6-bromopicolinate in 45% yield.
Synthesis of Ethyl 6-bromopicolinate
Synthesis of Ethyl 6-bromopicolinate
Ethyl 6-bromopicolinate Preparation Products And Raw materials
Preparation Productsethyl 6-cyclopropylpyridine-2-carboxylate
(6-BROMO-PYRIDIN-3-YL)-METHANOL 6-FLUORONICOTINIC ACID METHYL ESTER 2-Bromo-6-pyridinemethanol 6-Bromopyridine-2-carbaldehyde 6-Bromonicotinic acid 6-BROMOPYRIDINE-3-CARBOXYLIC ACID ETHYL ESTER 5-BROMOPYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER 6-BROMOPYRIDINE-2-ETHYL FORMATE ethyl 5-bromopyridine-2-carboxylate Ethyl formate 3-AMINO-6-BROMOPYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER 6-Bromopicolinic acid Ethyl 6-bromopicolinate 6-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER 3-BROMOPYRIDINE-4-CARBOXYLIC ACID ETHYL ESTER 5-Bromopyridine-3-carboxylic acid ethyl ester
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