ChemicalBook Product Catalog Organic Chemistry Hydrocarbons and derivatives Hydrocarbon halides 1-Chloromethyl naphthalene

1-Chloromethyl naphthalene

1-Chloromethyl naphthalene Basic information
Product Name:1-Chloromethyl naphthalene
Synonyms:1-(chloromethyl)-naphthalen;1-(Chloromethyl)naphthene;AKOS BBS-00004040;1-chloromethyl-naphthalen;1-Menaphthyl chloride;1-menaphthylchloride;1-(CHLOROMETHYL)NAPHTHALENE;1-CHLOROMETHYLNAPHTHYL
CAS:86-52-2
MF:C11H9Cl
MW:176.64
EINECS:201-678-2
Product Categories:API Intermediate;Naphthalene series;Aryl;Building Blocks;C9 to C12;Chemical Synthesis;Naphthalene derivatives;API intermediates;Halogenated Hydrocarbons;Organic Building Blocks;bc0001;86-52-2
Mol File:86-52-2.mol
1-Chloromethyl naphthalene Structure
1-Chloromethyl naphthalene Chemical Properties
Melting point 32 °C(lit.)
Boiling point 291 °C
density 1.18 g/mL at 25 °C(lit.)
refractive index n20/D 1.635(lit.)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, Ethyl Acetate (Slightly), Methanol (Sparingly)
form Liquid After Melting
color deep brown
Specific Gravity1.18
Water Solubility Insoluble in water.
Sensitive Moisture Sensitive
BRN 636885
InChIKeyXMWGTKZEDLCVIG-UHFFFAOYSA-N
LogP3.97 at 20℃
CAS DataBase Reference86-52-2(CAS DataBase Reference)
NIST Chemistry ReferenceNaphthalene, 1-(chloromethyl)-(86-52-2)
EPA Substance Registry SystemNaphthalene, 1-(chloromethyl)- (86-52-2)
Safety Information
Hazard Codes C,Xn
Risk Statements 21/22-34-36/37/38-36-20/21/22
Safety Statements 26-36/37/39-45-60-20-27
RIDADR UN 3261 8/PG 2
WGK Germany 3
RTECS QJ2800000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29036990
MSDS Information
ProviderLanguage
1-Chloromethyl naphthalene English
SigmaAldrich English
ACROS English
ALFA English
1-Chloromethyl naphthalene Usage And Synthesis
Chemical PropertiesSolid
Uses1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.
General DescriptionKinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
1-(chloromethyl)-5-nitro-naphthalene 9-ANTHRACENECARBONYL CHLORIDE Methylnaphthalene 6-CHLOROMETHYLBENZO(A)PYRENE 11-chloromethylbenzo(a)pyrene Chloromethyl methyl ether Naphthalene 1,4-BISCHLOROMETHYL-NAPHTHALENE 2-Ethoxynaphthalene-1-carbonyl chloride 1-CHLOROMETHYLPYRENE tert-Butyldimethylsilyl chloride 1-Chloromethyl naphthalene 5-BROMO-NAPHTHALENE-1-CARBONYL CHLORIDE 2-Methylbenzyl chloride 9,10-Bis(chloromethyl)anthracene ALPHA-CHLORO-9-ANTHRALDOXIME AURORA KA-4545 Chloromethane
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