Methyl 2-methylbutyrate

Methyl 2-methylbutyrate Basic information
Product Name:Methyl 2-methylbutyrate
Synonyms:2-METHYLBUTYRIC ACID METHYL ESTER;METHYL METHYLETHYLACETATE;METHYL DL-2-METHYLBUTYRATE;METHYL-2-METHYLBUTANOATE;METHYL 2-METHYLBUTYRATE;DL-METHYLBUTYRIC ACID METHYL ESTER;DL-2-METHYLBUTYRIC ACID METHYL ESTER;FEMA 2719
CAS:868-57-5
MF:C6H12O2
MW:116.16
EINECS:212-778-0
Product Categories:Flavors and Fragrances;M-N;Organics;C6 to C7;Carbonyl Compounds;Esters;Certified Natural ProductsFlavors and Fragrances;Alphabetical Listings
Mol File:868-57-5.mol
Methyl 2-methylbutyrate Structure
Methyl 2-methylbutyrate Chemical Properties
Melting point -91°C (estimate)
Boiling point 115 °C (lit.)
density 0.88 g/mL at 25 °C (lit.)
FEMA 2719 | METHYL 2-METHYLBUTYRATE
refractive index n20/D 1.393(lit.)
Fp 90 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Colorless to Almost colorless
Odorat 10.00 % in dipropylene glycol. ethereal estery fruity tutti frutti green apple lily of the valley powdery fatty
Odor Typefruity
JECFA Number205
BRN 1720409
LogP1.59
CAS DataBase Reference868-57-5(CAS DataBase Reference)
NIST Chemistry ReferenceButanoic acid, 2-methyl-, methyl ester(868-57-5)
EPA Substance Registry SystemButanoic acid, 2-methyl-, methyl ester (868-57-5)
Safety Information
Risk Statements 10-11
Safety Statements 16-23-33-29-7/9
RIDADR UN 3272 3/PG 3
WGK Germany 2
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29159000
MSDS Information
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Methyl 2-methylbutyrate English
SigmaAldrich English
ALFA English
Methyl 2-methylbutyrate Usage And Synthesis
DescriptionMethyl 2-methylbutyrate has a pungent, fruity odor with a sweet, fruity, apple-like taste at low levels. May be prepared from a mixture of esters including methyl 2-methylbutyrate; is obtained from isobutene, CO, and methanol under pressure, or from butene, CO, and an acid catalyst under pressure.
Chemical PropertiesMethyl-2-methylbutyrate has a sweet, fruity, apple-like odor and an apple-like taste at low concentrations.
OccurrenceThe levorotatory and the racemic forms are known. Reported found in fresh strawberry juice, apple, apricot, sour cherry, melon, pineapple, peas, baked potato, peppermint oil, spearmint oil, thymus, durian (Durio zibethinus), olive, mushroom, starfruit, prickly pear, dill herb, cashew apple, cherimoya, loquat, mountain papaya, cape gooseberry and rooibus tea (Aspalathus linearis). bilberry, strawberry, and cheeses
UsesDL-2-Methylbutyric Acid Methyl Ester is a volatile compound found in pineapples.
PreparationA mixture of esters including methyl-2-methylbutyrate is obtained from isobutene, CO and methanol under pressure, or from butene, CO and an acid catalyst under pressure.
DefinitionChEBI: Methyl (S)-2-Methylbutanoate is a fatty acid ester.
Aroma threshold valuesDetection: 0.92 to 4.4 ppb
Taste threshold valuesTaste characteristics at 7.5 ppm: sweet, berry, pineapple, etherial, lifting, fruity, tutti-fruitti and ripe with a fatty, green nuance
General DescriptionMethyl 2-methylbutyrate is an important odor-active constituent of pineapple, apple, cantaloupe, cucumber and strawberries.
Methyl 2-methylbutyrate Preparation Products And Raw materials
Raw materialsCARBON MONOXIDE-->Isobutylene
Methylparaben AZINPHOS-METHYL Methyl 2-bromo-2-methylpropionate Methyl Methyl butyrate METHYL 4-(4-AMINOPHENYL)BUTANOATE Basic Violet 1 Tribenuron methyl Kresoxim-methyl 2,2-Bis(hydroxymethyl)butyric acid Benzyldimethylcarbinyl butyrate Methyl 2,2-dimethylphenylacetate 2-Methyl butyric acid Methanol Methyl salicylate Methyl acrylate Methyl methacrylate METSULFURON METHYL

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