2-(Trimethylsilylmethyl)allyl acetate Usage And Synthesis
Chemical Properties
Clear colorless liquid
Physical properties
bp 68–70°C/6.5 mmHg;60–61°C/2.5 mmHg.
Uses
2-[(Acetoxymethyl)allyl]trimethylsilane was used in the cyclopentane synthesis via Pd(0)-catalyzed reactions with 2π acceptors.
Uses
precursor for palladium trimethylenemethane cycloaddition reactions.
Preparation
commercially available but expensive. Several preparations of (1) or the precursor alcohol (2) have been reported. The simplest involves the direct silylation of methallyl alcohol (eq 1).
2-(Trimethylsilylmethyl)allyl acetate Preparation Products And Raw materials
