ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic ketones 2'-Bromoacetophenone

2'-Bromoacetophenone

2'-Bromoacetophenone Basic information
Product Name:2'-Bromoacetophenone
Synonyms:Acetophenone, o-bromo-;ETHANONE, 1-(2-BROMOPHENYL)-;AKOS BBS-00004325;1-(2-BROMOPHENYL)ETHANONE;1-(2-BROMOMPHENYL)ETHANONE;1-ACETYL-2-BROMOBENZENE;O-BROMOACETOPHENONE;O-BROMOPHENYL METHYL KETONE
CAS:2142-69-0
MF:C8H7BrO
MW:199.04
EINECS:218-398-1
Product Categories:Building Blocks;C7 to C8;Acetophenone series;Chemical Synthesis;Ketones;Organic Building Blocks;Carbonyl Compounds;Aromatic Acetophenones & Derivatives (substituted);Benzene series;Adehydes, Acetals & Ketones;Bromine Compounds
Mol File:2142-69-0.mol
2'-Bromoacetophenone Structure
2'-Bromoacetophenone Chemical Properties
Melting point °C
Boiling point 116-117 °C (12 mmHg)
density 1.476 g/mL at 25 °C(lit.)
refractive index n20/D 1.568(lit.)
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
Specific Gravity1.476
color Clear pale yellow to orange
Water Solubility PRACTICALLY INSOLUBLE
BRN 1931534
InChIKeyPIMNFNXBTGPCIL-UHFFFAOYSA-N
CAS DataBase Reference2142-69-0(CAS DataBase Reference)
NIST Chemistry ReferenceEthanone, 1-(2-bromophenyl)-(2142-69-0)
Safety Information
Hazard Codes Xi,C
Risk Statements 36/37/38-34
Safety Statements 26-36-37/39-45-36/37/39
WGK Germany 3
Hazard Note Irritant
HS Code 29147090
MSDS Information
ProviderLanguage
1-(2-Bromophenyl)ethanone English
ACROS English
SigmaAldrich English
ALFA English
2'-Bromoacetophenone Usage And Synthesis
Chemical PropertiesClear pale yellow to orange liquid
Uses2-bromoacetophenone is employed in the selective derivatization of cytosine moieties for the determination of global DNA methylation by reversed phase high performance liquid chromatography with spectrofluorimetric detection.
Uses2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.
General Description2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.
2'-Bromoacetophenone Preparation Products And Raw materials
Preparation ProductsMethyl 2-bromobenzoate-->1-Bromo-2-(1,1-difluoroethyl)benzene-->1-PHENYL-1-PENTYNE-->ETHYL3-METHYL-2-INDOLECARBOXYLATE-->2-(2-Bromophenyl)-2-propanol-->1-BROMO-2-ETHYNYLBENZENE-->2-BROMO-5-NITROBENZOIC ACID-->Lonidamine-->1-(2-BroMophenyl)-3-diMethylaMino-2-propen-1-one-->Ethanone, 1-(2-bromophenyl)-2-fluoro- (9CI)-->Ethanone, 1-(2-bromophenyl)-2,2-dihydroxy--->4,4,4-Trifluoro-1-(2-bromophenyl)-1,3-butanedione
2-Bromobenzonitrile Acetyl-resveratrol Chalcone Acetylacetone 4'-Bromoacetophenone 1-(4-Bromophenyl)ethanone 1-Acetyl-4-Bromobenzene,OMEGA-BROMOACETOPHENONE 3-Nitroacetophenone M-BROMOACETOPHENONE,BROMOACETOPHENONE-3,3-BROMOACETOPHENONE,3'-BROMOACETOPHENONE 2'-Bromoacetophenone Acetophenone Acetyl coenzyme A sodium salt 4'-Methylacetophenone Bromobenzene L-PICEIN 2-Bromoacetophenone omega-Bromoacetophenone 2-Bromo-1-Phenylethanone,A-BROMOACETOPHENONE,ALPHA-BROMOACETOPHENONE,-Bromoacetophenon 2-AMINO-1-BROMO-3-CHLOROANTHRAQUINONE 2-Bromophenylacetic acid 4'-Hydroxyacetophenone 2'-Hydroxyacetophenone
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