3-Fluorotoluene

3-Fluorotoluene Basic information
Product Name:3-Fluorotoluene
Synonyms:1-fluoro-3-methyl-benzen;1-Methyl-3-fluorobenzene;3-fluoromethylbenzene;3-FLUOROTOLUENE;4,4-Diiso-Octanyl Diphenylamine;Fluorotoluene2;m-Fluro Toluene;3-Fluorotoluene m-Fluorotoluene
CAS:352-70-5
MF:C7H7F
MW:110.13
EINECS:206-524-8
Product Categories:alkyl Fluorine;Fluorinated Building Blocks;Halogenated Hydrocarbons;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;Aryl Fluorinated Building Blocks;Building Blocks;C7-C8;Chemical Synthesis;Aromatic Hydrocarbons (substituted) & Derivatives;Aryl;C7;Halogenated Hydrocarbons
Mol File:352-70-5.mol
3-Fluorotoluene Structure
3-Fluorotoluene Chemical Properties
Melting point -87 °C
Boiling point 115 °C(lit.)
density 0.991 g/mL at 25 °C(lit.)
refractive index n20/D 1.469(lit.)
Fp 49 °F
storage temp. Store below +30°C.
form clear liquid
color Colorless to Almost colorless
Specific Gravity0.991
Water Solubility immiscible
Merck 14,4180
BRN 1903631
LogP2.75
CAS DataBase Reference352-70-5(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-fluoro-3-methyl-(352-70-5)
EPA Substance Registry Systemm-Fluorotoluene (352-70-5)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-36/37/38
Safety Statements 16-26-36-37/39
RIDADR UN 2388 3/PG 2
WGK Germany 2
RTECS XT2578000
Hazard Note Flammable/Irritant
TSCA T
HazardClass 3
PackingGroup II
HS Code 29036990
MSDS Information
ProviderLanguage
1-Fluoro-3-methylbenzene English
SigmaAldrich English
ACROS English
ALFA English
3-Fluorotoluene Usage And Synthesis
Chemical Propertiesclear colorless to light yellow liquid
Uses3-Fluorotoluene was used in gas phase selective synthesis of 3-fluorobenzaldehyde. It was used in generation of tolyl cations by chemical ionization in mass spectrometry.
Synthesis Reference(s)Journal of the American Chemical Society, 72, p. 4809, 1950 DOI: 10.1021/ja01166a506
General DescriptionA colorless liquid with an aromatic odor. Boiling point 239°C. Flash point 63°F. Density 0.991 g / cm3---may float or sink in water.
Air & Water ReactionsHighly flammable.
Reactivity Profile3-Fluorotoluene may be incompatible with strong oxidizing and reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Generates toxic fluoride fumes when burned.
Health HazardInhalation causes upper respiratory irritation. Irritating to skin and eyes. May be absorbed through the skin. Prolonged exposure may result in systemic toxic effects. Harmful if swallowed.
Purification MethodsPurify it as for o-fluorotoluene. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]
3,4-Dibromo-5-fluorotoluene 2,4-Dibromo-6-fluorotoluene Tosufloxacin tosylate 3-AMINO-5-CHLOROBENZOTRIFLUORIDE 3,5-Dibromo-2-fluorotoluene ETHYL 3-FLUOROBENZOATE 3-BROMO-2,4,5,6-TETRAFLUOROBENZOTRIFLUORIDE 2,4-DIBROMO-5-FLUOROTOLUENE 2',3',4',5',6'-PENTAFLUOROACETOPHENONE 4,4'-DIMETHYLOCTAFLUOROBIPHENYL 1-CHLORO-2,4,5-TRIFLUORO-3-TRIFLUOROMETHYL-BENZENE 2,5-Dibromo-6-fluorotoluene 3-BROMO-5-CHLORO-4-IODOBENZOTRIFLUORIDE 2,3-DIAMINO-6-FLUOROTOLUENE fluoro jade PENTAFLUOROBENZYL BROMIDE 4-Amino-2-fluorobenzotrifluoride à-bromo-3-chloro-6-fluorotoluene

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