2-Bromo-3-methylbenzoic acid

2-Bromo-3-methylbenzoic acid Basic information

Product Name:	2-Bromo-3-methylbenzoic acid
Synonyms:	3-methyl-2-bromobenzoic acid;2-BROMO-3-METHYLBENZOIC ACID;2-Bromo-m-toluic acid (COOH=1);2-Bromo-m-toluic acid;2-Bromo-3-methyl;2-Bromo-3-methylbenzoic acid,97%;2-Bromo-3-methylbenz;2-Bromo-3-carboxytoluene
CAS:	53663-39-1
MF:	C8H7BrO2
MW:	215.04
EINECS:
Product Categories:	Building Blocks;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Phenyls & Phenyl-Het;C8;Carbonyl Compounds;Carboxylic Acids;Phenyls & Phenyl-Het;Benzoic acid;Organic acids;Acids & Esters;Bromine Compounds;Carboxylic Acids;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
Mol File:	53663-39-1.mol

2-Bromo-3-methylbenzoic acid Chemical Properties

Melting point	135-138 °C (lit.)
Boiling point	308.3±30.0 °C(Predicted)
density	1.599±0.06 g/cm3(Predicted)
storage temp.	Sealed in dry,Room Temperature
solubility	soluble in Methanol
form	Powder
pka	2.92±0.10(Predicted)
color	Off-white
CAS DataBase Reference	53663-39-1(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	22-24/25-37-26
WGK Germany	3
HazardClass	IRRITANT
HS Code	29163990

MSDS Information

Provider	Language
SigmaAldrich	English

2-Bromo-3-methylbenzoic acid Usage And Synthesis

Chemical Properties	Off-white powder
Uses	2-Bromo-3-methylbenzoic acid may be used to synthesize N-phenyl-3-methylanthranilic acid via copper-catalyzed amination reaction with aniline.
General Description	2-Bromo-4-nitrotoluene is formed as an intermediate during the synthesis of 2-bromo-3-methylbenzoic acid. 2-Bromo-3-methylbenzoic acid can be obtained from 2-bromo-4-nitrotoluene via Von-Richter reaction.

2-Bromo-3-methylbenzoic acid Preparation Products And Raw materials

Raw materials	Ethanol-->Hydrochloric acid-->Diethyl ether-->Acetic acid-->Chloroform-->Acetone-->Ammonia-->Carbon tetrachloride-->Potassium permanganate-->N-Bromosuccinimide-->Benzoyl peroxide-->Hexamethylenetetramine-->2-Bromo-m-xylene
Preparation Products	(2-Bromo-3-methylphenyl)(1H-indol-1-yl)methanone-->2-Bromo-3-methylbenzoyl chloride-->(2-bromo-3-methylphenyl)(pyrrolidin-1-yl)methanone

Methyl 2-bromo-3-methylbenzoate Methyl 2-BROMO-6-METHYLBENZOIC ACID METHYL ESTER 2-BROMO-6-METHYLBENZOIC ACID6-BROMO-O-TOLUIC ACID 2-Bromo-5-methylbenzoic acid 3-BROMO-4-METHYLBENZOIC ACID ETHYL ESTER 2-BROMO-6-METHYLBENZOIC ACID ETHYL ESTER 2-BROMO-4-METHYLBENZOIC ACID METHYL ESTER Ethyl 2-(Chlorosulfonyl)acetate 5-BROMO-2-METHYLBENZOIC ACID ETHYL ESTER Ascoric Acid ETHYL 2-BROMO-3-METHYLBENZOATE 3-bromo-5-methylbenzoic acid 2-AMINO-6-BROMO-5-METHYLBENZOIC ACID,6-AMINO-2-BROMO-3-METHYLBENZOIC ACID 2-BROMO-3-(TRIFLUOROMETHYL)BENZOIC ACID 4-BROMO-2METHYLBENZOIC ACID [JF-1] 4-BROMO-3-METHYLBENZOIC ACID ETHYL ESTER METHYL THIOPHENE-2-CARBOXYLATE

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