1-Amino-2-naphthol hydrochloride

1-Amino-2-naphthol hydrochloride Basic information
Product Name:1-Amino-2-naphthol hydrochloride
Synonyms:1-amino-2-naphthohydrochloride;1-AMINO-2-HYDROXYNAPHTHALENE HYDROCHLORIDE;1-AMINO-2-NAPHTHOL HCL;1-AMINO-2-NAPHTHOL HYDROCHLORIDE;2-HYDROXY-1-NAPHTHYLAMINE HYDROCHLORIDE;2-HYDROXY-1-NAPHTHYLAMMONIUM CHLORIDE;TIMTEC-BB SBB000347;1-AMINO-2-NAPHTHOL HYDROCHLORIDE, TECH., 90%
CAS:1198-27-2
MF:C10H10ClNO
MW:195.65
EINECS:214-830-8
Product Categories:Aromatic Hydrocarbons (substituted) & Derivatives;Organic Building Blocks;Oxygen Compounds;Phenols
Mol File:1198-27-2.mol
1-Amino-2-naphthol hydrochloride Structure
1-Amino-2-naphthol hydrochloride Chemical Properties
Melting point 250 °C (dec.)(lit.)
storage temp. Hygroscopic, Refrigerator, under inert atmosphere
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
color Purple
Water Solubility Soluble
Sensitive Light Sensitive
BRN 3699817
InChIKeyDEKREBCFNLUULC-UHFFFAOYSA-N
CAS DataBase Reference1198-27-2(CAS DataBase Reference)
EPA Substance Registry System2-Naphthalenol, 1-amino-, hydrochloride (1198-27-2)
Safety Information
Hazard Codes Xn,Xi
Risk Statements 20/21/22-36/37/38-40
Safety Statements 26-27-36/37/39
WGK Germany 3
RTECS QL3335000
Hazard Note Irritant
TSCA Yes
HS Code 29222990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1-Amino-2-naphthol hydrochloride Usage And Synthesis
Chemical Propertieslilac to light grey fluffy powder
Uses1-Amino-2-naphthol hydrochloride was used in a study on degradation of the azo dye Acid Orange 7 in batch anaerobic unstirred assay.
General Description1-Amino-2-naphthol undergoes condensation with methylene-substituted azaheterocycles in presence of an oxidizing agent to yield photochromic spirooxazines.
Purification MethodsCrystallise the salt from the minimum volume of hot water containing a few drops of stannous chloride in an equal weight of hydrochloric acid (to reduce atmospheric oxidation). Filter the solution and add half its volume of conc HCl and set aside. The salt crystallises almost quantitatively. Dry it in a vacuum in the dark (m 260o). The salt is more stable than the free base which has m 150o (darkening at 130o) and its O-methyl ether has m 49o and b 159-159o/9mm. [Desai et al. J Chem Soc 324 1938, Beilstein 13 H 666, 13 I 268, 13 II 408, 13 III 1875, 13 IV 2080.]
1-Amino-2-naphthol hydrochloride Preparation Products And Raw materials
Preparation ProductsSpiro(2H-indole-2,3'-(3H)naphth(2,1-B)(1,4)oxazine), 6'-(2,3-dihydro-1H-indol-1-yl)-1,3-dihydro-1,3,3-trimethyl-
2-AMINO-7-NAPHTHOL HYDROCHLORIDE 1-Amino-2-naphthol 1,1'-Bi-2-naphthol INDOINE BLUE Vitamin K5 2-Methyl-4-amino-1-naphthol hydrochloride 2-METHYL-4-AMINO-1-NAPHTHOL HYDROCHLORIDE (6S)-6-(propyl-(2-thiophen-2-ylethyl)amino)tetralin-1-ol hydrochloride Topotecan hydrochloride ALTRENOGEST CRESYL VIOLET PERCHLORATE 1-AMINO-2-NAPHTHOL HYDROCHLORIDE, (2-HYDROXY-1-NAPHTHYLAMINE HYDROCHLORIDE) 5-AMINO-1-NAPHTHOL HYDROCHLORIDE Phenmedipham AMINO ACIDS CHLOROPHOSPHONAZO III 2-AMINO-1-NAPHTHOL HYDROCHLORIDE,2-AMINO-1-NAPHTHOL HYDROCHLORIDE 98+% 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile Meldola's blue

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