Benzo-15-crown-5

Benzo-15-crown-5 Basic information
Product Name:Benzo-15-crown-5
Synonyms:Benzo-15-crown-5, 99% 2.5GR;CROWN ETHER/BENZO-15-CROWN-5 FOR SYNTHES;2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-15,17,19-triene;1,2-[Oxybis(ethyleneoxyethyleneoxy)]benzene;2,5,8,11,14-Pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-triene;6,7,9,10,12,13,15,16-Octahydro-5,8,11,14,17-pentaoxa-5H-benzocyclopentadecene;Benzo-15-crown-5,99%;denzo15c5
CAS:14098-44-3
MF:C14H20O5
MW:268.31
EINECS:237-947-6
Product Categories:crown ether;Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry;Chelation/Complexation Compounds;Crown Ethers;Synthetic Reagents
Mol File:14098-44-3.mol
Benzo-15-crown-5 Structure
Benzo-15-crown-5 Chemical Properties
Melting point 78-80 °C (lit.)
Boiling point 371.47°C (rough estimate)
density 1.1846 (rough estimate)
refractive index 1.4825 (estimate)
storage temp. Inert atmosphere,Room Temperature
form Powder or Flakes
color Almost white to light gray
Water Solubility partially soluble
Sensitive Hygroscopic
BRN 1624106
InChIKeyDSFHXKRFDFROER-UHFFFAOYSA-N
CAS DataBase Reference14098-44-3(CAS DataBase Reference)
NIST Chemistry ReferenceBis(1,4,7,10,13-benzopentaoxacyclopentadecin, 2,3,5,6,8,9,11,12-octahydro-)(14098-44-3)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-36-26
WGK Germany 3
RTECS DI5400000
3-10
Hazard Note Irritant
HS Code 29329995
MSDS Information
Benzo-15-crown-5 Usage And Synthesis
Chemical PropertiesALMOST WHITE TO LIGHT GREY POWDER OR FLAKES
UsesBenzo-15-crown-5 is used in synthetic chemistry. It plays a major role and involved in complexation through ether oxygen. It is used in phase-transfer catalyst system. It is involved in 'Host-Guest' chemistry to identify the move of essential elements in the body. It can play the part of very complicated biological reactions such as enzyme functions, which finds application in the development of new pharmaceuticals.
ApplicationBenzo-15-crown-5 can be used for sol-gel material extraction to separate lithium isotopes, for making static detection sensors for formic acid gases, and as metal ion complexing agent and phase transfer reagent.
Preparationsynthesis of Benzo-15-crown-5: benzo-15-crown-5 can be produced using Williamson synthesis reaction, featured by interaction between catechol (orto-dihydroxybenzene) and tetraethylene glycol dichloride (1,10-dichloro-3,6,9-trioxadecane) over sodium hydroxide in the n-butanol media (30-h inertatmosphere boiling). The yield of benzo-15-crown-5 produced by this method is 62%, with the basic substance's mass fraction of 95%.
Production of Macrocyclic Polyether Benzo-15-Crown-5 and its Functional Derivatives
DefinitionChEBI: Benzo-15-crown-5 is a crown ether that is 15-crown-5 ortho-fused to a benzene ring.
Thianaphthene Benzoic acid, C12-15-alkyl esters (BENZO-15-CROWN-5)-4'-YLAMINE (2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLOPENTADECIN-15-YLMETHYL)(TRIPHENYL)PHOSPHONIUM CHLORIDE RARECHEM AL BZ 0432 4-ACRYLOYLAMIDOBENZO-15-CROWN-5, 99 4-TERT-BUTYLBENZO-15-CROWN-5 2,3-NAPHTHO-15-CROWN-5 4-Aminobenzo-15-crown-5 hydrochloride (BENZO-15-CROWN-5)-4'-YL BROMIDE 4'-FORMYLBENZO-15-CROWN 5-ETHER (BENZO-15-CROWN-5)-4'-CARBOXYLIC ACID,(BENZO-15-CROWN 5-ETHER)-4'-CARBOXYLIC ACID 4'-(2'',4''-DINITRO-6''-TRIFLUOROMETHYLPHENYL)-AMINOBENZO-15-CROWN-5 4-VINYLBENZO-15-CROWN-5 1,3-DI(2,3,5,6,8,9,11,12-OCTAHYDRO-1,4,7,10,13-BENZOPENTAOXACYCLOPENTADECIN-15-YL)PROP-2-EN-1-ONE 4'-ACETYLBENZO-15-CROWN 5-ETHER 4'-AMINO-5'-NITROBENZO-15-CROWN-5 4'-ISOCYANATOBENZO-15-CROWN-5

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