CYCLOOCTENE OXIDE

CYCLOOCTENE OXIDE Basic information
Product Name:CYCLOOCTENE OXIDE
Synonyms:1,2-EPOXYCYCLOOCTANE 97+%;9-Oxabicyclo[6.1.0]nonane, Epoxycyclooctane;Cyclooctene oxide,99%;Cyclooctene oxide,9-Oxabicyclo[6.1.0]nonane, Epoxycyclooctane;Cyclooctene oxide, 99% 25GR;Cyclooctene Oxide 9-Oxabicyclo[6.1.0]nonane;Cyclooctene oxide 99%;Epoxycyclooctane for synthesis
CAS:286-62-4
MF:C8H14O
MW:126.2
EINECS:206-010-3
Product Categories:Building Blocks;Chemical Synthesis;Epoxides;Organic Building Blocks;Oxygen Compounds
Mol File:286-62-4.mol
CYCLOOCTENE OXIDE Structure
CYCLOOCTENE OXIDE Chemical Properties
Melting point 53-56 °C(lit.)
Boiling point 55 °C5 mm Hg(lit.)
density 0.9090 (rough estimate)
refractive index 1.4540 (estimate)
Fp 133 °F
storage temp. 2-8°C
solubility soluble in Methanol
form powder to crystal
color White to Almost white
BRN 103543
CAS DataBase Reference286-62-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xn,F
Risk Statements 22-36/38-11
Safety Statements 26-37/39
RIDADR UN 1325 4.1/PG 3
WGK Germany 2
10-21
HazardClass 4.1
PackingGroup III
HS Code 29109000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
CYCLOOCTENE OXIDE Usage And Synthesis
Chemical PropertiesCOLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS
Synthesis Reference(s)The Journal of Organic Chemistry, 43, p. 1689, 1978 DOI: 10.1021/jo00403a015
Tetrahedron Letters, 27, p. 2617, 1986 DOI: 10.1016/S0040-4039(00)84599-2
Purification MethodsIt can be distilled in vacuum, and the solidified distillate can be sublimed in vacuum below 50o. It has a characteristic odour. [IR: Cope et al. J Am Chem Soc 74 5884 1952, cf trans-isomer: Cope et al. J Am Chem Soc 79 3905 1957, Reppe et al. Justus Liebigs Ann Chem 560 1 1948].
HEPTACHLOREPOXIDE-13C1 HEPTACHLOR EPOXIDE (ISOMER B) (13C1) diketocoriolin B cis-Cyclooctene oxide 1,2,5,6-DIEPOXYCYCLOOCTANE DICYCLOPENTADIENE DIOXIDE, ENDO OXY-CHLORDENE coriolin (+)-TRANS-HEPTACHLOROEPOXIDE (+)-OXY-CHLORDANE CYCLOOCTENE OXIDE Dicyclopentadiene diepoxide CRINIPELLIN A CIS-HEPTACHLOREPOXIDE EXO-, ISOMER B 6ALPHA, 7ALPHA-EPOXY-2-OXABICYCLO[3.3.0]OCTAN-3-ONE PHOTODIELDRIN CHLORDECONE-5B-HYDRO (+)-TRANS-HEPTACHLOREPOXIDE

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