|
| | 9-Anthraldehyde Basic information |
| | 9-Anthraldehyde Chemical Properties |
| Melting point | 103-105 °C (lit.) | | Boiling point | 305.09°C (rough estimate) | | density | 1.0701 (rough estimate) | | refractive index | 1.6324 (estimate) | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | solubility | Soluble in toluene. | | form | Crystalline Powder or Needles | | color | Yellow | | Sensitive | Air Sensitive | | BRN | 639167 | | Stability: | Stable. Incompatible with strong bases, strong oxidizing agents. | | InChIKey | YMNKUHIVVMFOFO-UHFFFAOYSA-N | | CAS DataBase Reference | 642-31-9(CAS DataBase Reference) | | NIST Chemistry Reference | 9-Anthracenecarboxaldehyde(642-31-9) | | EPA Substance Registry System | 9-Anthracenecarboxaldehyde (642-31-9) |
| | 9-Anthraldehyde Usage And Synthesis |
| Chemical Properties | yellow powder | | Uses | 9-Anthraldehyde is used to prepare asymmetrical tridentate Schiff base ligands, 2-(9-anthrylmethyl-ideneamino)-4-methyl-phenol and functionalized ligand like 2-(anthracen-9-ylidene)-4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione through Knoevenangel condensation with the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopentene-1,3-dione. It is also used as an intermediate for dyes, pigment, active pharmaceutical ingredients and other organic compounds. Further, it is involved in the Diels Alder reaction with benzenediazonium-2-carboxylate. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 53, p. 4587, 1988 DOI: 10.1021/jo00254a035 | | General Description | The Diels-Alder reaction of 9-anthracenecarboxaldehyde with benzenediazonium-2-carboxylate was studied. | | Purification Methods | 9-Anthraldehyde [642-31-9] M 206.2, m 104-105o. Crystallise the aldehyde from acetic acid or EtOH. [Masnori et al. J Am Chem Soc 108 1126 1986, Beilstein 7 IV 1738.] |
| | 9-Anthraldehyde Preparation Products And Raw materials |
|
