Sodium bis(2-methoxyethoxy)aluminiumhydride

Sodium bis(2-methoxyethoxy)aluminiumhydride Basic information

Product Name:	Sodium bis(2-methoxyethoxy)aluminiumhydride
Synonyms:	DIHYDROBIS-(2-METHOXYETHOXY)-ALUMINATE SODIUM;VITRIDE;VITRIDE(R);VITRIDE(TM);Aluminate(1-),dihydrobis(2-methoxyethanolato-O,O’)-,sodium;dihydrobis(2-methoxyethanolato-o,o’)-aluminate(1-sodium;SODIUM BIS(2-METHOXYETHOXY)ALUMINUM HYDRIDE: 70% W/W IN TOLUENE;Sodium dihydrobis(2-methoxyethoxy)aluminate, 70% w/w in toluene
CAS:	22722-98-1
MF:	C6H16AlNaO4
MW:	202.16
EINECS:	245-178-2
Product Categories:	Pyrazoles;metal hydride;Organometallics;Al (Alminum) Compounds;Classes of Metal Compounds;Reduction;Synthetic Organic Chemistry;Typical Metal Compounds
Mol File:	22722-98-1.mol

Sodium bis(2-methoxyethoxy)aluminiumhydride Chemical Properties

Boiling point	396-402°C
density	1.036 g/mL at 25 °C
vapor pressure	21 mm Hg ( 20 °C)
Fp	40 °F
storage temp.	Flammables area
solubility	Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
form	Viscous Liquid
color	Clear to slightly hazy, colorless to light amber
Specific Gravity	1.036
explosive limit	7%
Water Solubility	reacts
Sensitive	Air & Moisture Sensitive
Hydrolytic Sensitivity	8: reacts rapidly with moisture, water, protic solvents
Merck	14,8564
Exposure limits	ACGIH: TWA 20 ppm OSHA: Ceiling 300 ppm; TWA 200 ppm NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
InChIKey	OKUDBXZACZBZJE-UHFFFAOYSA-N
LogP	-2.64 at 25℃ and pH7
CAS DataBase Reference	22722-98-1(CAS DataBase Reference)
EPA Substance Registry System	Aluminate(1-), dihydrobis[2-(methoxy-.kappa.O)ethanolato-.kappa.O]-, sodium (22722-98-1)

Safety Information

Hazard Codes	F,C
Risk Statements	11-14/15-34-48/20-63-65-67
Safety Statements	26-36/37/39-43-45-62-46-16-9
RIDADR	UN 3399 4.3/PG 1
WGK Germany	2
F	1-10
TSCA	Yes
HazardClass	4.3
PackingGroup	I
HS Code	29319090

MSDS Information

Provider	Language
Sodium dihydro-bis-(2-methoxyethoxy)aluminate	English
ACROS	English
SigmaAldrich	English
ALFA	English

Sodium bis(2-methoxyethoxy)aluminiumhydride Usage And Synthesis

Chemical Properties	clear to slightly hazy, colorless to light amber
Uses	Reducing agent.
Uses	Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.
Uses	Red-Al^? sodium bis(2-methoxyethoxy)aluminum hydride can be used as: ?????? A tosyl deprotecting agent.??????? A catalyst for crosslinking of polyvinylsilanes (PVS) by Si-Si dehydrocoupling reaction in the presence of group 4 metallocene complexes.??????? A reducing reagent for the synthesis of optically active N-protected amino alcohols and peptide alcohols.
General Description	Red-Al^? sodium bis(2-methoxyethoxy)aluminum hydride [NaAlH₂(OCH₂CH₂OCH₃)₂] is used as a versatile reducing agent in organic synthesis. It is used to reduce: Aldehydes, ketones, esters, and anhydrides to primary alcohols. Ketoximes and aldoximes to primary amines. Cyclic compounds such as lactones and epoxides to diols. It is also used as a catalyst in the ring-opening polymerization reactions.

Sodium bis(2-methoxyethoxy)aluminiumhydride Preparation Products And Raw materials

Preparation Products

MORPHOLINE-3,4-DICARBOXYLIC ACID 4-TERT-BUTYL ESTER-->ALLURA RED AC-->METHYL 7-[(3RS)-3-HYDROXY-5-OXOCYCLOPENT-1-ENYL]HEPTANOATE-->Anthracene, 9-ethyl-9,10-dihydro-9,10-dimethyl-

Sodium bis(2-methoxyethoxy)aluminiumhydride

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