(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE)

(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) Basic information
Product Name:(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE)
Synonyms:2,2'-ISOPROPYLIDENEBIS[(4S)-4-TERT-BUTYL-2-OXAZOLINE];(S,S)-(-)-2,2'-(DIMETHYLMETHYLENE)BIS(4-TERT-BUTYL-2-OXAZOLINE);(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE);(S,S)-2,2'-ISOPROPYLIDENE-BIS(4-TERT-BUTYL-2-OXAZOLINE);(S,S)-(-)-2,2-BIS(4-TERT-BUTYL-2-OXAZOLIN-2-YL)PROPANE;2,2-isopropylidenebis((4S)-4-tert-butyl-2-oxazol;Isopropylidenebisbutyloxazoline;(S,S)-(-)-2,2-Isopropylidenebis(4-Tert-Butyl-2-Oxazolin
CAS:131833-93-7
MF:C17H30N2O2
MW:294.43
EINECS:
Product Categories:organic building block;BOX series;Asymmetric Synthesis;Synthetic Organic Chemistry;Amino Alcohols & Deriv.;Chiral Nitrogen;Chiral Reagents;CHIRAL CHEMICALS
Mol File:131833-93-7.mol
(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) Structure
(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) Chemical Properties
Melting point 89-91 °C(lit.)
Boiling point 350.4±25.0 °C(Predicted)
density 1.04±0.1 g/cm3(Predicted)
refractive index -118 ° (C=1, CHCl3)
storage temp. Inert atmosphere,Room Temperature
form Crystalline Powder
pka5.69±0.70(Predicted)
color White to light yellow
optical activity[α]20/D 120°, c = 5 in chloroform
CAS DataBase Reference131833-93-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) Usage And Synthesis
UsesChiral catalyst for asymmetric synthesis. C2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
(S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) Preparation Products And Raw materials
Raw materials(S,S)-2,2'-METHYLENEBIS(4-TERT-BUTYL-2-OXAZOLINE)-->DIMETHYLMALONONITRILE-->DIMETHYLMALONYL CHLORIDE-->(S)-TERT-LEUCINOL-->Dimethylmalonic acid-->Iodomethane
Preparation ProductsOxazole, 2,2'-(1-methylethylidene)bis[4,5-dihydro-4-methyl-, (4S,4'S)-
(S,S)-2,2'-METHYLENEBIS(4-TERT-BUTYL-2-OXAZOLINE) 2,2-Bis[(4R)-4-isopropyl-2-oxazolin-2-yl]propane N-BENZYLQUININIUM CHLORIDE 2,2'-methylenebis[(4S)-4-tert-butyl-2-oxazoline] (R,R)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) (R)-TERT-LEUCINOL (4R)-4-T-BUTYL-2-METHYL 2-OXAZOLINE 2-(1-(HYDROXYMETHYL)ETHYL)-OXAZOLINE& (S,S)-(-)-2,2'-ISOPROPYLIDENEBIS(4-TERT-BUTYL-2-OXAZOLINE) 2-Ethyl-2-oxazoline 2-ISOPROPYL-2-OXAZOLINE

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