TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE

TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE Basic information
Product Name:TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE
Synonyms:TRITYL HEXAFLUORO-PHOSPHATE;TRITYLIUM HEXAFLUOROPHOSPHATE;TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE;triphenyl-methyliuhexafluorophosphate(1-);Trityl hexafluorophosphate, Tritylium hexafluorophosphate;Triphenylmethylium·hexafluorophosphate;Trityl cation·hexafluorophosphate;Triphenylcarbenium hexafluorophosphate,99%
CAS:437-17-2
MF:C19H15F6P
MW:388.29
EINECS:207-112-0
Product Categories:
Mol File:437-17-2.mol
TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE Structure
TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE Chemical Properties
Melting point ~150 °C (dec.) (lit.)
storage temp. 2-8°C
Water Solubility Soluble in water. (27 g/L) at 25°C.
Sensitive Moisture Sensitive
BRN 4344297
EPA Substance Registry SystemMethylium, triphenyl-, hexafluorophosphate(1-) (437-17-2)
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
8-10
TSCA Yes
HazardClass 8
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE Usage And Synthesis
Chemical PropertiesOCHRE TO ORANGE POWDER
UsesTriphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
PHOSPHORUS TRIFLUORIDE TRIPHENYLCARBENIUM HEXAFLUOROPHOSPHATE Hexafluorophosphoric acid PHOSPHORUS PENTAFLUORIDE

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