ChemicalBook Product Catalog Pharmaceutical intermediates Heterocyclic compound (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE

(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Basic information
Product Name:(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE
Synonyms:(s,s)-4-phenyl-α-(4-phenyloxazolidin-2-ylidene)-2-oxazoline-2-acetonitrile;(4S)-(+)-Phenyl-alpha-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile 97%;(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE;(S,S)-4-PHENYL-ALPHA-(4-PHENYLOXAZOLIDIN-2-YLIDENE)-2-OXAZOLINE-2-ACETONITRILE;(S,S)-4-phe-A-(4-phe.oxazolidin-ylidene) -oxazoline-acetonit.;(S,S)-(+)-4-PHENYL-ALPHA-(4-PHENYLOXAZOL IDIN-2 -YLIDENE)-2-OXAZOLINE-2-ACETONITR;(4s)-(+)-phenyl-α-[(4s)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile;(2Z)-2-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-2-[(4S)-4-phenyl-1,3-oxazolidin-2-ylidene]acetonitrile
CAS:150639-33-1
MF:C20H17N3O2
MW:331.37
EINECS:
Product Categories:
Mol File:150639-33-1.mol
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Structure
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Chemical Properties
Melting point 146-148 °C(lit.)
Boiling point 457.5±45.0 °C(Predicted)
density 1.27±0.1 g/cm3(Predicted)
storage temp. 2-8°C
pka3.30±0.70(Predicted)
optical activity[α]20/D +364°, c = 1 in chloroform
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Usage And Synthesis
UsesLigand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
General Description(4S)-(+)-Phenyl-α-[(4S)-phenyloxazolidin-2-ylidene]-2-oxazoline-2-acetonitrile is a C2-symmetric chiral bisoxazoline (BOX) ligand.
(+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE Preparation Products And Raw materials
MYCOLIDE (+)-(4S)-PHENYL-ALPHA-[(4S)-PHENYLOXAZOLIDIN-2-YLIDENE]-2-OXAZOLINE-2-ACETONITRILE 2-Ethyl-2-oxazoline (S)-(+)-1-AMINO-1-PHENYL-2-METHOXYETHANE 2-ISOPROPENYL-2-OXAZOLINE 99+% Oxazoline 3-ETHOXYACRYLONITRILE
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