PINDONE

PINDONE Basic information
Product Name:PINDONE
Synonyms:1,3-Indandione, 2-pivaloyl-;1,3-Indandione, 2-pivalyl-;1H-Indene-1,3(2H)-dione, 2-(2,2-dimethyl-1-oxopropyl)-;2-(2,2-dimethyl-1-oxopropyl)-1H-indene-1,3-(2H)-dione;2-(2,2-dimethyl-1-oxopropyl)-1h-indene-1,3(2h)-dione;2-(2,2-dimethyl-1-oxopropyl)-1h-indene-3(2h)-dione;2-(2,2-Dimethylpropanoyl)-1H-indene-1,3(2H)-dione;2-(Trimetil-acetil)-indan-1,3-dione
CAS:83-26-1
MF:C14H14O3
MW:230.26
EINECS:201-462-8
Product Categories:
Mol File:83-26-1.mol
PINDONE Structure
PINDONE Chemical Properties
Melting point 108-110°
Boiling point 312.25°C (rough estimate)
density 1.1914 (rough estimate)
refractive index 1.5557 (estimate)
storage temp. APPROX 20°C
solubility Soluble in most organic solvents (Worthing and Hance, 1991)
form neat
pka3.47±0.10(Predicted)
color Bright yellow crystals
Water Solubility 18 ppm at 25 °C (Gunther et al., 1968)
Merck 13,7526
BRN 2051258
Exposure limitsNIOSH REL: TWA 0.1 mg/m3, IDLH 100 mg/m3; OSHA PEL: TWA 0.1 mg/m3; ACGIH TLV: TWA 0.1 mg/m3
EPA Substance Registry SystemPindone (83-26-1)
Safety Information
Hazard Codes T,N
Risk Statements 25-48/25-50/53
Safety Statements 37-45-60-61
RIDADR 3027
WGK Germany 3
RTECS NK6300000
HazardClass 6.1(b)
PackingGroup III
HS Code 29143990
Hazardous Substances Data83-26-1(Hazardous Substances Data)
ToxicityLD50 orally in male rats: 280 mg/kg (Gaines)
IDLA100 mg/m3
MSDS Information
PINDONE Usage And Synthesis
Chemical PropertiesPindone is a bright yellow crystalline solid or powder. May turn yellow-brown on contact with air. Nearly odorless.
UsesInsecticide; rodenticide
UsesPindone may be used as an analytical reference standard for the quantification of the analyte in biological samples using different chromatography techniques.
DefinitionChEBI: Pindone is a member of indanones and a beta-triketone.
General DescriptionYellow solid or powder.
Air & Water ReactionsInsoluble in water.
Reactivity ProfileKetones, such as PINDONE, are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.
Health HazardPindone is a vitamin K antagonist and causes inhibition of prothrombin formation, which results in hemorrhage. There are no reports of effects in humans.
Fire HazardFlash point data for PINDONE are not available, but PINDONE is probably combustible.
Safety ProfilePoison by ingestion, intravenous, and parenteral routes. Causes reduced blood clotting, which leads to hemorrhaging. Used as an anticoagulant and rodenticide. When heated to decomposition it emits acrid smoke and irritating fumes. See also WARFARIN.
Potential ExposurePindone is used as an anticoagulant and rodenticide. A potential danger to those involved in manufacture, formulation and application of this chemical
ShippingUN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesKetone substances are incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, nitrated amines; azo, diazo, azido compounds, carbamates, organic cyanates.
Waste DisposalUse a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
PINDONE Preparation Products And Raw materials
1-Phenylpentan-3-one Diphacinone-Na 3-O-TOLYL-PROPIONALDEHYDE 2,2-DIMETHYL-3,5-HEXANEDIONE 4,4-DIMETHYL-3-OXO-PENTANAL 2-PROPYL-1-INDANONE, 98 1-O-TOLYL-BUTANE-1,3-DIONE 2'-ETHYLPROPIOPHENONE 2,4-DIMETHYL-3-HEXANONE 2-METHYL-1-INDANONE 3-ETHYL-2,4-PENTANEDIONE 2-ACETYL-1,3-INDANEDIONE 1-O-TOLYL-PENTAN-1-ONE 2-METHYL-1-PHENYL-BUTANE-1,3-DIONE 2,2,4-TRIMETHYL-3-PENTANONE Triformylmethane 2-ETHYL-1-INDANONE 3-N-PROPYL-2,4-PENTANEDIONE

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