ChemicalBook Product Catalog Biochemical Engineering Amino Acids and Derivatives Proline derivatives cis-4-Hydroxy-D-proline

cis-4-Hydroxy-D-proline

cis-4-Hydroxy-D-proline Basic information
Product Name:cis-4-Hydroxy-D-proline
Synonyms:D-trans-Hydroxyproline;(2R,4R)-(-)-4-HYDROXY-2-PYRROLINECARBOXYLIC ACID;(2R,4R)-4-HYDROXYPYRROLIDINE-2-CARBOXYLIC ACID;(4R,2R)-4-HYDROXY-PYRROLIDINE-2-CARBOXYLIC ACID;D-ALLO-4-HYDROXY-2-PYRROLIDINE-CARBOXYLIC ACID;D-ALLO-HYDROXYPROLINE;D-CIS-4-HYDROXYPROLINE;D-CIS-HYDROXYPROLINE
CAS:2584-71-6
MF:C5H9NO3
MW:131.13
EINECS:219-963-5
Product Categories:Amino Acids & Derivatives;Chiral Reagents;Chiral reagent;Chiral Compound;Carboxylic Acids;Heterocycles;Carboxylic Acids;Pyrrolidines;chiral
Mol File:2584-71-6.mol
cis-4-Hydroxy-D-proline Structure
cis-4-Hydroxy-D-proline Chemical Properties
Melting point 243 °C (dec.)(lit.)
alpha 58 º (c=2, water 24 ºC)
Boiling point 242.42°C (rough estimate)
density 1.3121 (rough estimate)
refractive index 1.4300 (estimate)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Water (Slightly)
pka2.14±0.40(Predicted)
form Powder
color White
Water Solubility 5 g/100 mL
BRN 81439
InChIKeyPMMYEEVYMWASQN-QWWZWVQMSA-N
LogP-1.840 (est)
CAS DataBase Reference2584-71-6(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25-22-36/37/39-27-26
WGK Germany 3
F 10
HS Code 29339900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
cis-4-Hydroxy-D-proline Usage And Synthesis
Chemical Propertieswhite powder
Usescis-4-Hydroxy-D-proline (cas# 2584-71-6) is a compound useful in organic synthesis.
DefinitionChEBI: D-proline in which a hydrogen at the 4-position of the pyrrolidine ring is substituted by a hydroxy group (R-configuration).
Biochem/physiol ActionsCis-4-Hydroxy-D-proline may be used as a starting material for the 13-step synthesis of new conformationally restricted PNA adenine monomer and the synthesis of N-Benzyl pyrrolidinyl sordaricin derivatives. Cis-4-Hydroxy-D-proline is a substrate that may be used to study the specificity and kinetics of D-alanine dehydrogenase. Cis-4-Hydroxy-D-proline may be used to analyze the substrate specificity of amino acid transporter PAT1.
cis-4-Hydroxy-D-proline Preparation Products And Raw materials
Preparation Products1-Pyrrolidinecarboxylicacid,4-amino-2-methyl-,1,1-dimethylethylester,(2S-trans)-(9CI)-->N-CBZ-CIS-4-HYDROXY-D-PROLINE METHYL ESTER-->Methyl (R)-1-Boc-4,4-difluoropyrrolidine-2-carboxylate-->TRANS-4-HYDROXY-L-PROLINE METHYL ESTER-->(3R,5S)-tert-butyl 3-aMino-5-fluoropiperidine-1-carboxylate
CIS-4-HYDROXY-D-PROLINE HCL ,cis-4-Hydroxy-D-proline hydrochloride CIS-4-HYDROXY-L-PROLINE,CIS-4-HYDROXY-L-PROLINE NATURAL ISOMER ALLO-D-HYDROXYPROLINE ETHYL ESTER HYDROCHLORIDE AKOS 323 trans-4-Hydroxy-D-proline alpha-Cypermethrin FMOC-D-HYP(TBU)-OH D-Proline FMOC-CIS-4-HYDROXY-D-PROLINE,N-ALPHA-9-FLUORENYLMETHOXYCARBONYL-CIS-4-HYDROXY-D-PROLINE,N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-CIS-4-HYDROXY-L-PROLINE N-tert-Butoxycarbonyl-cis-4-hydroxy-D-proline methyl ester cis-4-Hydroxy-D-proline L-Proline cis-Octahydro-isoindole AKOS 90635 L-Hydroxyproline L-PROLINE-(4-3H(N)) 2-(R)-CARBOETHOXY-4-(R)-HYDROXYPYRROLIDINE CHLOROPHOSPHONAZO III
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