4-METHOXYPHENETHYL ALCOHOL

4-METHOXYPHENETHYL ALCOHOL Basic information
Product Name:4-METHOXYPHENETHYL ALCOHOL
Synonyms:2-(p-Methoxyphenyl)ethanol;2-[p-Methoxyphenyl]ethylalcohol;4-Methoxyphenethyl alcohol,2-(4-Methoxyphenyl)ethanol;4-Methoxyphenethyl acohol;AKOS 90987;4-(2-HYDROXYETHYL)ANISOLE;4-METHOXYPHENETHYL ALCOHOL;4-METHOXYPHENYLETHYL ALCOHOL
CAS:702-23-8
MF:C9H12O2
MW:152.19
EINECS:211-866-6
Product Categories:Aromatics;Benzhydrols, Benzyl & Special Alcohols
Mol File:702-23-8.mol
4-METHOXYPHENETHYL ALCOHOL Structure
4-METHOXYPHENETHYL ALCOHOL Chemical Properties
Melting point 26-28 °C(lit.)
Boiling point 334-336 °C(lit.)
density 1.058±0.06 g/cm3 (20 ºC 760 Torr)
refractive index 1.536-1.538
Fp >230 °F
storage temp. Sealed in dry,Room Temperature
solubility Soluble in DMSO, Methanol.
form Liquid After Melting
pka15.00±0.16(Predicted)
color Clear light brown
FreezingPoint 23.0 to 28.0 ℃
BRN 2043563
LogP1.393 (est)
CAS DataBase Reference702-23-8(CAS DataBase Reference)
EPA Substance Registry System4-Methoxybenzeneethanol (702-23-8)
Safety Information
Safety Statements 24/25
WGK Germany 3
TSCA Yes
HS Code 29062990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
4-METHOXYPHENETHYL ALCOHOL Usage And Synthesis
Chemical Propertiesclear light brown liquid after melting
Uses4-Methoxyphenethyl alcohol was used in the preparation of 4-(2-iodoethyl)phenol, by refluxing it with 47% hydriodic acid. It may be used in the preparation of (2R*,4R*)-1-n-butyl-2-methyl-4-(2-oxopyrrolidin-1-yl)-6-methoxy-1,2,3,4-tetrahydroquinoline and (2R*,4S*)-1-n-butyl-2-methyl-4-(2-oxopyrrolidin-1-yl)-6-methoxy-1,2,3,4- tetrahydroquinoline.
Uses2-(4-Methoxyphenyl)ethanol is used as an internal standard in the fluorous biphasic catalysis reaction. It is used in the preparation of 4-(2-iodoethyl)phenol, by refluxing it with 47% hydriodic acid. It may be used in the preparation of (2R*,4R*)-1-n-butyl-2-methyl-4-(2-oxopyrrolidin-1-yl)-6-methoxy-1,2,3,4-tetrahydroquinoline and (2R*,4S*)-1-n-butyl-2-methyl-4-(2-oxopyrrolidin-1-yl)-6-methoxy-1,2,3,4- tetrahydroquinoline. It is used for foods, perfumes, and cosmetics.
Uses4-Methoxyphenethyl alcohol has a flavor and aroma of fresh citrus juice and may be used for perfumes, foods, and cosmetics.
Synthesis Reference(s)Journal of the American Chemical Society, 82, p. 3222, 1960 DOI: 10.1021/ja01497a062
Tetrahedron Letters, 33, p. 7465, 1992 DOI: 10.1016/S0040-4039(00)60796-7
General Description(R)-1-(4-methoxyphenyl)ethanol {(R)-MOPE, 4-Methoxyphenethyl alcohol, 1-(4-methoxyphenyl)ethanol } is formed during the biocatalytic anti-Prelog enantioselective reduction of 4-methoxyacetophenone (MOAP) using immobilized Trigonopsis variabilis AS2.
4-METHOXYPHENETHYL ALCOHOL Preparation Products And Raw materials
Preparation Products3-(4-METHOXY-PHENYL)-PROPIONALDEHYDE-->4-METHOXYPHENETHYL BROMIDE-->DIGLYCIDYL ETHER-->N,N-dimethyl-4-methoxyphenylethylamine-->(p-Methoxyphenethyl)hydrazine-->Benzene, 1-fluoro-4-[2-(4-methoxyphenyl)ethyl]-
2,3,4-TRIMETHOXYPHENYLACETIC ACID 1-(4-METHOXYPHENYL)-1-CYCLOHEXANECARBOXYLIC ACID AKOS AU36-M255 STERIGMATOCYSTIN 3-FLUORO-4-METHOXYPHENETHYL ALCOHOL 2-BROMO-4,5-DIMETHOXYPHENYLACETIC ACID Methyl 3-(4-methoxyphenyl)oxirane-2-carboxylate 4-Ethoxy-3-methoxyphenylacetic acid 4-ethoxy-3-methoxyphenethyl alcohol (+)-Bicuculline 3,5-DIMETHYL-4-METHOXYPHENETHYL ALCOHOL 97% 2,4,6-TRIMETHOXYPHENYLACETIC ACID 3-Hydroxy-4-methoxyphenylacetic acid AFLATOXIN G1 DL-4-HYDROXY-3-METHOXYMANDELIC ACID 6,7-DIMETHOXY-1,4-DIHYDRO-3H-ISOCHROMEN-3-ONE 1-(4-METHOXYPHENYL)-1-CYCLOPENTANECARBOXYLIC ACID 2-HYDROXY-1-(4-METHOXYPHENYL)-1-ETHANONE

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