ChemicalBook Product Catalog Flavors and fragrances Synthetic fragrances Carboxylic acids and esters Aliphatic dicarboxylic acid esters CINNAMYL FORMATE

CINNAMYL FORMATE

CINNAMYL FORMATE Basic information
Product Name:CINNAMYL FORMATE
Synonyms:(2E)-3-Phenyl-2-propenyl formate;2-Propen-1-ol, 3-phenyl-, formate;2-Propen-1-ol,3-phenyl-,formate;3-phenyl-2-propen-1-oformate;3-Phenyl-2-propen-1-yl formate;3-phenyl-2-propen-1-ylformate;Cinnamyl alcohol, formate;Cinnamyl methanoate
CAS:104-65-4
MF:C10H10O2
MW:162.19
EINECS:203-223-3
Product Categories:Alphabetical Listings;C-D;Flavors and Fragrances;104-65-4
Mol File:104-65-4.mol
CINNAMYL FORMATE Structure
CINNAMYL FORMATE Chemical Properties
Boiling point 250-254 °C (lit.)
density 1.08 g/mL at 25 °C (lit.)
vapor pressure 2.666Pa at 25℃
refractive index n20/D 1.553(lit.)
FEMA 2299 | CINNAMYL FORMATE
Fp >230 °F
storage temp. Inert atmosphere,Store in freezer, under -20°C
Odorat 100.00 %. balsam fruity floral green herbal cinnamyl narcissus
Odor Typebalsamic
Water Solubility 725.1mg/L at 25℃
JECFA Number649
LogP2.3 at 25℃
EPA Substance Registry System2-Propen-1-ol, 3-phenyl-, formate (104-65-4)
Safety Information
WGK Germany 2
RTECS UD5530000
toxicityThe acute oral LD50 in rats was reported as 2.9 g/kg (2.38-3.54 g/kg) and the acute dermal LD50 in rabbits as > 5 g/kg (Denine. 1973).
MSDS Information
ProviderLanguage
SigmaAldrich English
CINNAMYL FORMATE Usage And Synthesis
Chemical PropertiesCinnamyl formate has a balsamic, fruital-floral odor and bittersweet taste reminiscent of apple.
OccurrenceReported found in narcissus.
PreparationBy esterification of cinnamyl alcohol with formic acid.
Aroma threshold valuesDetection at 1.0%: cinnamon spicy, slightly balsamic, cherry fruity with berry and tropical nuances.
Taste threshold valuesTaste characteristics at 5 ppm: sweet, cinnamon-like, astringent, with woody resinous and balsamic nuances.
General DescriptionCinnamyl formate is an α,β-unsaturated?ester that can be used as a flavoring agent and a fragrance ingredient.
Flammability and ExplosibilityNotclassified
Safety ProfileModerately toxic by ingestion. See also ESTERS. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.
MetabolismCinnamyl formate is hydrolysed by porcine pancreatic lipase 2.6 times more rapidly than is cinnamyl oleate under identical conditions (Brockerhoff, 1970).
CINNAMYL FORMATE Preparation Products And Raw materials
Raw materialsFormic acid-->CINNAMIC ALCOHOL
4,6-DIPHENYLTHIENO[3,4-D]-1,3-DIOXOL-2-ONE 5,5-DIOXIDE 4-HYDROXY-3-PHENYL-2(5H)-FURANONE FEMA 2296 Phenylmaleic anhydride Pulvinicanhydride 3-PHENYLACRYLIC ANHYDRIDE RHIZOCARPIC ACID FEMA 2302 CINNAMYL FORMATE Cinnamyl cinnamate CINNAMYL ISOBUTYRATE 3,4,5-TRIMETHOXYCINNAMIC ACID ANHYDRIDE 3,4-DIHYDRO-1,2-NAPHTHALENEDICARBOXYLIC ANHYDRIDE ALPHA-N-AMYL CINNAMYL ACETATE Cinnamyl propionate VULPINIC ACID 2,3-DIPHENYLMALEIC ANHYDRIDE ANTHRANILIC ACID CINNAMYL ESTER
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