3-BROMOCYCLOHEXENE

3-BROMOCYCLOHEXENE Basic information

Product Name:	3-BROMOCYCLOHEXENE
Synonyms:	1-Bromo-2-cyclohexene;2-Cyclohexenyl bromide;3-Bromo-1-cyclohexene;1,2,3,4-TETRAHYDROBROMOBENZENE;2-CYCLOHEXEN-1-YL BROMIDE;(+/-)-3-BROMOCYCLOHEXENE;3-BromocycL;3-BROMOCYCLOHEXENE
CAS:	1521-51-3
MF:	C6H9Br
MW:	161.04
EINECS:
Product Categories:
Mol File:	1521-51-3.mol

3-BROMOCYCLOHEXENE Chemical Properties

Melting point	131-134 °C
Boiling point	57-58 °C/12 mmHg (lit.)
density	1.4 g/mL at 25 °C (lit.)
refractive index	n20/D 1.528(lit.)
Fp	130 °F
storage temp.	-20°C
form	Solid
color	White to off-white
Water Solubility	Not miscible or difficult to mix in water.
BRN	635953
InChIKey	AJKDUJRRWLQXHM-UHFFFAOYSA-N
CAS DataBase Reference	1521-51-3(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	26-36
RIDADR	UN 1993 3/PG 3
WGK Germany	3
F	10
HazardClass	3
PackingGroup	III
HS Code	29038900

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

3-BROMOCYCLOHEXENE Usage And Synthesis

Chemical Properties	clear colorless to yellow liquid
Uses	3-Bromocyclohexene was used in the synthesis of N-tert-butoxycarbonyl-O-cyclohexyl-L-tyrosine. It was also used in the synthesis of enantiopure cyclohexitols such as muco-quercitol, D-chiro-inocitol and allo-inocitol.
Synthesis Reference(s)	Tetrahedron Letters, 26, p. 3863, 1985 DOI: 10.1016/S0040-4039(00)89271-0

3-BROMOCYCLOHEXENE Preparation Products And Raw materials

Raw materials	2-CYCLOHEXEN-1-OL-->Cyclohexene-->Methyl phenyl sulfone-->Cyclohexene oxide
Preparation Products	3-Bromopropionyl Isocyanate-->TRANS-1,2-DIBROMOCYCLOHEXANE-->GLYCINE ANHYDRIDE-->2-Cyclohexen-1-one-->3-(2-Cyclohexenyl)quinoline

RARECHEM AQ BC 9074 RARECHEM AQ BC 9054 RARECHEM AQ BC 9100 2,6-DIBROMO-4,8-DICYANOTRICYCLO[3.3.1.0(1,5)]NONA-3,7-DIENE RARECHEM AQ C6 0008 BROMOCONDURITOL RARECHEM AL BO 2084 RARECHEM AQ BC 9072 3-BROMOCYCLOHEXENE 4,8-DIBROMOBICYCLO[3.3.1]NONA-2,6-DIENE-2,6-DICARBONITRILE RARECHEM AQ BC 9016 RARECHEM AQ BC 9101 RARECHEM AQ BC 9073 RARECHEM AQ BC 9103 RARECHEM AL BO 2062 4,8-DIBROMO-2,6-DIPHENYLBICYCLO[3.3.1]NONA-2,6-DIENE SPECS AE-534/30057033 RARECHEM AQ TC 8016

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