ChemicalBook Product Catalog Organic Chemistry Organometallic compounds Organomagnesium PHENYLMAGNESIUM CHLORIDE

PHENYLMAGNESIUM CHLORIDE

PHENYLMAGNESIUM CHLORIDE Basic information
Product Name:PHENYLMAGNESIUM CHLORIDE
Synonyms:PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN;Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran;PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF;Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran;PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER;PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN;Phenylmagnesiumchloride,2-3MinTHF;PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN
CAS:100-59-4
MF:C6H5ClMg
MW:136.86
EINECS:202-868-8
Product Categories:Organometallics;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Aryl;Grignard Reagents;Organometallic Reagents;grignard reagent
Mol File:100-59-4.mol
PHENYLMAGNESIUM CHLORIDE Structure
PHENYLMAGNESIUM CHLORIDE Chemical Properties
Melting point 89-90℃
Boiling point 230℃ (8 Torr)
density 0.98 g/mL at 20 °C
Fp 1 °F
storage temp. 2-8°C
Water Solubility It reacts violently with water.
Sensitive Air & Moisture Sensitive
Merck 14,7298
BRN 3587900
InChIKeyGQONLASZRVFGHI-UHFFFAOYSA-M
CAS DataBase Reference100-59-4(CAS DataBase Reference)
EPA Substance Registry SystemMagnesium, chlorophenyl- (100-59-4)
Safety Information
Hazard Codes F,C
Risk Statements 14-19-20/21/22-34-67-65-63-48/20-11-40-37
Safety Statements 26-36/37/39-45-62-33-16
RIDADR UN 2924 3/PG 2
WGK Germany 2
F 10
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29319090
Hazardous Substances Data100-59-4(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
PHENYLMAGNESIUM CHLORIDE Usage And Synthesis
Chemical Propertiesyellowish-brown to dark brown solution
UsesIn organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
UsesPhenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.
UsesGrignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
DefinitionChEBI: Phenylmagnesium chloride is an arylmagnesium halide.
General DescriptionThis product has been enhanced for energy efficiency.
PHENYLMAGNESIUM CHLORIDE Preparation Products And Raw materials
Preparation Products5-METHOXY-2-NITROPHENYLBORONIC ACID-->5-CYANO-2-NITROPHENYLBORONIC ACID-->5-(BROMOMETHYL)-2-NITROPHENYLBORONIC ACID-->4-BROMO-2-NITROPHENYLBORONIC ACID-->4-METHOXY-2-NITROPHENYLBORONIC ACID-->5-METHYL-2-NITROPHENYLBORONIC ACID-->4-Phenylpyridine-->4-FLUORO-2-NITROPHENYLBORONIC ACID-->1-Phenylnonane-->1,1-DIPHENYLETHANOL-->(5-bromo-2-fluorophenyl)(phenyl)methanol
1,1-DIMETHYLPROPYLMAGNESIUM CHLORIDE Hexylmagnesium chloride 2-METHYL-2-PHENYLPROPYLMAGNESIUM CHLORIDE O-TOLYLMAGNESIUM CHLORIDE Magnesium monochloride PHENYLMAGNESIUM CHLORIDE, 25% SOLNIN THF 4-(METHYLTHIO)PHENYLMAGNESIUM CHLORIDE 3-[BIS(TRIMETHYLSILYL)AMINO]PHENYLMAGNESIUM CHLORIDE chloro(p-chlorophenyl)magnesium 3 5-DIMETHYOXYPHENYLMAGNESIUM CHLORIDE 3-[bis(trimethylsilyl)amino]phenylmagnesium chloride solution PHENYLMAGNESIUM CHLORIDE M-TOLYLMAGNESIUM CHLORIDE 3-FLUORO-2-METHYLPHENYLMAGNESIUM CHLORI& Tetrahydrofuran p-(2-Methoxyethyl)phenylmagnesium chloride 3,4-DIMETHYLPHENYLMAGNESIUM CHLORIDE P-TOLYLMAGNESIUM CHLORIDE
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