3-Ethylamino-4-methylphenol

3-Ethylamino-4-methylphenol Basic information
Product Name:3-Ethylamino-4-methylphenol
Synonyms:1-Methyl-2-(ethylamino)-4-hydroxybenzene;2-Ethylamino-4-hydroxy-1-methylbenzene;3-Ethylamino-p-cresol;3-(ethylamino)-4-methyl-pheno;3-Ethylamino;3-ETHYLAMINO-PARAMETHYLPHENOL;3-(ETHYLAMINO)-P-CRESOL;3-ETHYLAMINO-4-CRESOL
CAS:120-37-6
MF:C9H13NO
MW:151.21
EINECS:204-391-0
Product Categories:Building Blocks;C9 to C20+;Intermediates of Dyes and Pigments;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Organic Building Blocks;Oxygen Compounds;Phenols
Mol File:120-37-6.mol
3-Ethylamino-4-methylphenol Structure
3-Ethylamino-4-methylphenol Chemical Properties
Melting point 85-87 °C (lit.)
Boiling point 135-140°C 3mm
density 1.0406 (rough estimate)
refractive index 1.5380 (estimate)
Fp 135-140°C/3mm
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka10.66±0.18(Predicted)
form powder to crystal
color White to Gray to Red
Water Solubility Insoluble in water.
BRN 3241548
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference120-37-6(CAS DataBase Reference)
NIST Chemistry ReferencePhenol, 3-(ethylamino)-4-methyl-(120-37-6)
EPA Substance Registry System3-(Ethylamino)-4-methylphenol (120-37-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 2
RTECS SL4105000
TSCA Yes
HS Code 29222990
MSDS Information
ProviderLanguage
2-Ethylamino-4-hydroxytoluene English
SigmaAldrich English
ALFA English
3-Ethylamino-4-methylphenol Usage And Synthesis
Chemical Propertiespurple solid
Uses3-Ethylamino-4-methylphenol was used in the synthesis of rhodol by undergoing condensation reaction with 2-(2,4-dihydroxybenzoyl)benzoic acid.
General DescriptionPurple solid.
Air & Water Reactions3-Ethylamino-4-methylphenol may be sensitive to prolonged exposure to air. . Insoluble in water.
Reactivity ProfileAn amine and phenol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.
Fire HazardFlash point data for 3-Ethylamino-4-methylphenol are not available. 3-Ethylamino-4-methylphenol is probably combustible.
3-Ethylamino-4-methylphenol Preparation Products And Raw materials
Preparation ProductsSULFORHODAMINE G-->Solvent Red 229-->Basic Red 1:1
3,5-Dimethylphenol Methyl Diethylaminosulfur trifluoride 3-Aminopyridine 2-Aminoacetophenone p-Cresol Diethylaminoethanol 4-Aminophenol Kresoxim-methyl Pirimiphos-methyl 4-Aminoantipyrine 2-Aminophenol Methyl salicylate Methyl acetate Methyl bromide METSULFURON METHYL 2-Diethylaminoethanethiol 4-Dimethylaminopyridine

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