1-[(2,5-dimethoxyphenyl)azo]-2-naphthol

1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Basic information
Product Name:1-[(2,5-dimethoxyphenyl)azo]-2-naphthol
Synonyms:Blueberry red pigment;C.I.12156;C.I.Solvent Red 80;1-((2,5-DiMethoxyphenyl)diazenyl)naphthalen-2-ol;1-[(2,5-dimethoxyphenyl)azo]-2-naphthol;Solvent Red 80.;1-(2,5-DIMETHYLPHENYLAZO)-2-NAPHTHOL;CITRUSRED
CAS:6358-53-8
MF:C18H16N2O3
MW:308.33
EINECS:228-778-9
Product Categories:dyestuff
Mol File:6358-53-8.mol
1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Structure
1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Chemical Properties
Melting point 155-157°
Boiling point 448.73°C (rough estimate)
density 1.2510 (rough estimate)
refractive index 1.5700 (estimate)
pka13.61±0.50(Predicted)
form neat
Colour Index 12156
BRN 4510811
LogP3.129 (est)
IARC2B (Vol. 8, Sup 7) 1987
EPA Substance Registry SystemCitrus Red No. 2 (6358-53-8)
Safety Information
Hazard Codes Xn
Risk Statements 40
Safety Statements 45
WGK Germany 3
RTECS QL3675000
Hazardous Substances Data6358-53-8(Hazardous Substances Data)
Toxicitycitrus red is a color used for coloring the skin of mature oranges. This compound has been described as being carcinogenic.
MSDS Information
1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Usage And Synthesis
UsesTo color orange skins.
Preparation2,5-Dimethoxyaniline diazotization, and Naphthalen-2-ol coupling.
DefinitionChEBI: Citrus Red No.2 is a member of azobenzenes.
General DescriptionOrange to yellow solid or dark red powder.
Air & Water ReactionsAzo dyes can be explosive when suspended in air at specific concentrations. Insoluble in water.
Reactivity Profile1-[(2,5-dimethoxyphenyl)azo]-2-naphthol is an azo compound. Toxic gases are formed by mixing compounds containing azo groups with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides.
HazardPossible carcinogen.
Health HazardACUTE/CHRONIC HAZARDS: When heated to decomposition it emits toxic fumes of NOx.
Fire HazardFlash point data for 1-[(2,5-dimethoxyphenyl)azo]-2-naphthol are not available. 1-[(2,5-dimethoxyphenyl)azo]-2-naphthol is probably combustible.
Safety ProfileConfirmed carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx
Properties and Applicationsorange to red. Melting point of 155 ~ 157 ℃. Slightly soluble in water, slightly soluble in ethanol and rape oil.
1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Preparation Products And Raw materials
Raw materials2,5-Dimethoxyaniline-->2-Naphthol
White pigment Gardenia blue pigment Hibiscetin Grape skin red pigment Monascus Red Pigments Cherry red pigment Purple Rice Pigment Yellowish pigments Amaranth red aluminium lake Tartrazine 5,8-Dihydroxy-2-[(1R)-1-hydroxy-4-methyl-pent-3-enyl]naphthalene-1,4-dione fruit-green Acid Red 27 2'-(Dibenzylamino)-6'-(diethylamino)fluoran Solvent Red 8 1-[(2,5-dimethoxyphenyl)azo]-2-naphthol Solvent Red 1 5-[(4-chlorobenzoyl)amino]-4-hydroxy-3-[[4-[(2-hydroxy-7-sulpho-1-naphthyl)azo]-2,5-dimethoxyphenyl]azo]naphthalene-2,7-disulphonic acid

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