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Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate

Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Basic information
Product Name:Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
Synonyms:DILUDINE;DIETHYL 2,6-DIMETHYL-1,4-DIHYDRO-3,5-PYRIDINEDICARBOXYLATE;DIETHYL 2,6-DIMETHYL-1,4-DIHYDROPYRIDINEDICARBOXYLATE;DIETHYL 1,4-DIHYDRO-2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE;AURORA 4780;3,5-DICARBETHOXY-2,6-DIMETHYL-1,4-DIHYDROPYRIDINE;3,5-BIS(CARBOETHOXY)-2,6-DIMETHYL-1,4-DIHYDROPYRIDINE;2,6-DIMETHYL-1,4-DIHYDROPYRIDINE-3,5-DICARBOXYLIC ACID DIETHYL ESTER
CAS:1149-23-1
MF:C13H19NO4
MW:253.29
EINECS:214-561-6
Product Categories:Pyridines, Pyrimidines, Purines and Pteredines;C9 to C46;Pharmaceutical Intermediates;Heterocyclic Building Blocks;Pyridines;C9 to C46;Heterocyclic Building Blocks;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, pharmaceutical intermediates;Building Blocks;C13 to C15;Chemical Synthesis;Heterocycle-Pyridine series;1149-23-1
Mol File:1149-23-1.mol
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Structure
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Chemical Properties
Melting point 178-183 °C(lit.)
Boiling point 351.8±42.0 °C(Predicted)
density 1.104±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in organic solvents.
form Solid
pka3.50±0.70(Predicted)
color Yellow
λmax374nm(EtOH)(lit.)
InChIInChI=1S/C13H19NO4/c1-5-17-12(15)10-7-11(13(16)18-6-2)9(4)14-8(10)3/h14H,5-7H2,1-4H3
InChIKeyLJXTYJXBORAIHX-UHFFFAOYSA-N
SMILESC1(C)NC(C)=C(C(OCC)=O)CC=1C(OCC)=O
CAS DataBase Reference1149-23-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 2
RTECS US7970100
HS Code 29333990
ToxicityLD50 oral in dog: > 12gm/kg
MSDS Information
ProviderLanguage
SigmaAldrich English
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Usage And Synthesis
Chemical PropertiesLight green solid
Uses3,5-Dicarboethoxy-2,6-dimethyl-1,4-dihydropyridine is a dihydropyridine derivative that have been tested for antimicrobial activities.
UsesDiethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is a hydrogen source in conjugate reduction and organocatalytic reductive amination. It is used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Preparation Products And Raw materials
Raw materialsEthanol-->Hexamethylenetetramine
Preparation ProductsGlutaraldehyde-->Imazosulfuron-->Nilvadipine-->Nicardipine-->Benidipine-->pyridine-2,3,5,6-tetracarboxylic acid
DIETHYL 4-ETHYL-1,4-DIHYDRO-2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLATE Dacthal Pyridine hydrobromide Nimodipine N,N-Dimethylformamide DIETHYL 1,4-DIHYDRO-2,6-DIMETHYL-4-(4-F& AURORA 4028 Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Diethyl2,6-dimethyl-4-phenyl-1,4-dihydropyridine-3,5-dicarboxylate DIETHYL 4-(4-METHOXYPHENYL)-2,6-DIMETHYL-1,4-DIHYDRO-3,5-PYRIDINEDICARBOXYLATE 2,6-Lutidine DIETHYL 1,4-DIHYDRO-2,4,6-TRIMETHYL-3,5-PYRIDINEDICARBOXYLATE Celiprolol Dimethyl carbonate Ethylene glycol diethyl ether AURORA 3177 Dimethyl phthalate Dimethyl sulfate
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