TRI(2-FURYL)PHOSPHINE

TRI(2-FURYL)PHOSPHINE Basic information
Reaction
Product Name:TRI(2-FURYL)PHOSPHINE
Synonyms:SALOR-INT L308749-1EA;TRIS(2-FURYL)PHOSPHINE;TRI(2-FURYL)PHOSPHINE;Tri(2-furyl)phospine;Tri(2-furyl)phosphine,97%;Tri(2-furyL;TFP / Tri(2-furyl)phosphine;Tri(fur-2-yl)phosphine
CAS:5518-52-5
MF:C12H9O3P
MW:232.17
EINECS:628-036-8
Product Categories:Achiral Phosphine;Aryl Phosphine;organophosphorus ligand;Aromatics;Chelating Agents & Ligands;Heterocycles;Ligand;Phosphine Ligands;Synthetic Organic Chemistry;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:5518-52-5.mol
TRI(2-FURYL)PHOSPHINE Structure
TRI(2-FURYL)PHOSPHINE Chemical Properties
Melting point 59-64 °C (lit.)
Boiling point 136 °C/4 mmHg (lit.)
Fp 136°C/4mm
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form solid
color faintly brown
Sensitive air sensitive
BRN 1577564
InChIInChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChIKeyDLQYXUGCCKQSRJ-UHFFFAOYSA-N
SMILESP(C1=CC=CO1)(C1=CC=CO1)C1=CC=CO1
CAS DataBase Reference5518-52-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-24/25
WGK Germany 3
10-23
TSCA No
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
TRI(2-FURYL)PHOSPHINE Usage And Synthesis
Reaction
  1. Useful ligand for C-C coupling reactions.
  2. Ligand used for the alkynylation of thioesters.
  3. Ligand used for enol ester formation.
  4. Ligand for palladium-catalyzed 3-Component coupling.
  5. Ligand for palladium-catalyzed C-C coupling reaction.
  6. Ligand for trans-olefin formation.
  7. Olefin formation from N-tosylhydrazones and benzyl halides.
  8. C-H arylation/alkenylation of 1-substituted tetrazoles. 
Reactions of 5518-52-5_1
Reactions of 5518-52-5_2
Chemical PropertiesTRI(2-FURYL)PHOSPHINE is white to light yellow crystal powde
UsesTRI(2-FURYL)PHOSPHINE is a phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.
Usessuzuki reaction
TRI(2-FURYL)PHOSPHINE Preparation Products And Raw materials
Preparation ProductsPhosphine oxide,tri-2-furanyl-
Trimethyl 3,3',3''-phosphinetriyltripropanoate hydrochloride tris(2-carboxaldehyde)triphenylphosphine TRI-P-TOLYLPHOSPHINE PHOSPHOROUS ACID TRI-O-CRESYL ESTER tris(2-fluorophenyl)phosphane Tri(o-tolyl)phosphine TRI(2,5-XYLYL)PHOSPHINE Tri(2-furyl)phosphine oxide Tri(2-furyl)phosphine selenide Tri(3-furyl)phosphine selenide Tri(3-furyl)phosphine BIS(2-FURYL)PHOSPHINE Tri(3-furyl)phosphine sulfide TRI(2-FURYL)PHOSPHINE Tri(3-furyl)phosphine oxide Tri(2-furyl)phosphine sulfide Phosphine 1-(5-[BIS-(5-ACETYL-FURAN-2-YL)-PHOSPHINOYL]-FURAN-2-YL)-ETHANONE

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