4-Methylaminophenol sulfate

4-Methylaminophenol sulfate Basic information
Product Name:4-Methylaminophenol sulfate
Synonyms:METOL;METOL(TM);METHOL;BIS-(N-METHYL-4-HYDROXYANILINIUM) SULFATE;ARMOL;ELON;ECOL(R);GENOL
CAS:55-55-0
MF:C7H11NO5S
MW:221.23
EINECS:200-237-1
Product Categories:Industrial/Fine Chemicals;Pharmaceutical Raw Materials
Mol File:55-55-0.mol
4-Methylaminophenol sulfate Structure
4-Methylaminophenol sulfate Chemical Properties
Melting point 260 °C (dec.)(lit.)
density 1.577
refractive index 1.6510 (estimate)
storage temp. −20°C
solubility H2O: 50 mg/mL, clear
form Powder
color white to faintly beige
Water Solubility 50 g/L (20 ºC)
Sensitive Air Sensitive
Merck 14,6017
BRN 3919382
Stability:Stability Combustible. Incompatible with strong oxidizing agents, acids, acid halides.
CAS DataBase Reference55-55-0(CAS DataBase Reference)
EPA Substance Registry Systemp-Methylaminophenol sulfate (55-55-0)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-43-48/22-50/53
Safety Statements 36/37-46-60-61
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS SL8650000
8
Autoignition Temperature989 °F
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29222900
MSDS Information
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4-Methylaminophenol sulfate English
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4-Methylaminophenol sulfate Usage And Synthesis
DescriptionMetol is contained in black-and-white film developers and caused contact dermatitis in photographers.
Chemical PropertiesWhite crystalline powder
UsesPhotographic developer; dyeing furs.
UsesMetol is a black-and-white photographic developer; dyeing furs; as pigment in hair dyes.
Uses4-(Methylamino)phenol sulfate is a photographic developer used in black and white photography. It is also used as tone developers in developing agents. Further, it is used in oxidative hair dye formulations.
Uses4-methylaminophenol sulfate is used as a photographic developer and fur dye.
DefinitionChEBI: The sulfate salt of 4-methylaminophenol.
General DescriptionOff-white crystalline solid. Sensitive to light.
Air & Water ReactionsWater soluble.
Reactivity ProfileIn aqueous solution behaves as an acid. Materials in this group are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.
HazardEye and skin irritant.
Fire HazardFlash point data for 4-Methylaminophenol sulfate are not available but 4-Methylaminophenol sulfate is probably combustible.
Contact allergensMetol is contained in black and white film developers and caused contact dermatitis in photographers.
Purification MethodsCrystallise this photographic developer from H2O (needles m 250-260o) (its solubility is 5% at 20o and 17% at 100o) or MeOH. It is used for determining Ag. [Palit et al. Indian J Chem, Sect B 28 64 1989.]
4-Methylaminophenol sulfate Preparation Products And Raw materials
Raw materials4-Aminophenol
Acetaminophen METOL SULFATE sulfate Vanadyl sulfate Sodium sulfate D-Glucosamine sulfate 4-Methylaminophenol sulfate 4-Aminophenol 4-METHYLAMINOPHENOLSULFATE = P-METHYLAMINOPHENOLSULFATE = METOL n-Dodecyl alcohol, sulfated 2-Aminophenol Aluminum sulfate GOLD COAST SOLUTION NO 1 3-Aminophenol Zinc sulfate heptahydrate Ammonium sulfate Magnesium sulfate heptahydrate Barium sulfate

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