CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Basic information
Reaction
Product Name:CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
Synonyms:CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I);CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE;BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE;BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE;IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE;CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I);VASKA'S COMPLEX;carbonylchlorobis(triphenylphosphine)-iridiu
CAS:14871-41-1
MF:C37H30ClIrOP2
MW:780.25
EINECS:238-941-6
Product Categories:Ir
Mol File:14871-41-1.mol
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Structure
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Chemical Properties
Melting point 215°C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol
form crystal
color lemon yellow
λmax385nm(lit.)
InChIKeyKMVALWICXMGTQO-UHFFFAOYSA-M
CAS DataBase Reference14871-41-1(CAS DataBase Reference)
EPA Substance Registry SystemIridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1)
Safety Information
Risk Statements 20/21/22
Safety Statements 22-24/25
RIDADR UN2811
WGK Germany 3
TSCA Yes
HS Code 2931.90.6000
HazardClass 6.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Usage And Synthesis
Reaction
  1. Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
  2. Catalyst for the selective hydrogenation of myrcene.
  3. Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
  4. Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
  5. Hydrogen atom transfer catalyst for radical cyclizations.
  6. Complex for photocatalytic alkane dehydrogenation.
  7. Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
  8. Catalyst for chemoselective reductive alkynylation of tertiary amides.
Reactions of 14871-41-1_1
Reactions of 14871-41-1_2
Reactions of 14871-41-1_3

Chemical PropertiesGREEN FINE CRYSTALLINE POWDER
UsesCarbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Preparation Products And Raw materials
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I) Carbonyldihydrotris(triphenylphosphine)ruthenium Carbonylchlorohydrotris(triphenylphosphine)ruthenium Bis(triphenylphosphine)palladium(II) chloride Chloro(1,5-cyclooctadiene)rhodium(I) dimer Diphenylphosphine CARBON MONOXIDE CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Iridium(III) chloride hydrate Iridium

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