SILVER CHLORATE

SILVER CHLORATE Basic information
Product Name:SILVER CHLORATE
Synonyms:Argentous chlorate;SILVER CHLORATE;SILVER (I) CHLORATE;SILVER CHLORATE, 99.9+%;Chloric acid silver(I) salt;Silver chlorate >=99.9% trace metals basis
CAS:7783-92-8
MF:AgClO3
MW:191.32
EINECS:232-034-9
Product Categories:Materials Science;Metal and Ceramic Science;Metal and Ceramic Science;Salts;Silver Salts;Silver Salts
Mol File:7783-92-8.mol
SILVER CHLORATE Structure
SILVER CHLORATE Chemical Properties
Melting point 230 °C(lit.)
density 4.43 g/mL at 25 °C(lit.)
storage temp. 2-8°C
form white tetragonal crystals
Water Solubility g/100g solution H2O: 14.46 (25°C) [KRU93]; g/100g H2O: 10.4 (10°C), 15.3 (20°C), 26.8 (40°C) [LAN05]; slightly soluble alcohol [MER06]
Merck 13,8581
Safety Information
Hazard Codes O,Xi
Risk Statements 8-36/37/38
Safety Statements 17-26-36
RIDADR UN 1479 5.1/PG 2
WGK Germany 3
HazardClass 5.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
SILVER CHLORATE Usage And Synthesis
Chemical PropertiesSilver Chlorate is a yellow to yellowish-gray powder. Con- tains 78% silver. Light-sensitive. Soluble in ammonium hydroxide, nitric acid; insoluble in alcohol and water.
UsesSilver Chlorate is used in organic synthesis as an effective oxidizing agent for certain organic Compounds.
HazardOxidizing agent, may react violently when shocked or heated, store away from combustible materials. Toxic by ingestion.
Purification MethodsRecrystallise the chlorate three times from water (10mL/g at 15o; 2mL/g at 80o). Store it in the dark. [Nicholson & Holley Inorg Synth II 4 1946, Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 1037 1963.]
SILVER CHLORATE Preparation Products And Raw materials
MERCURIC NITRATE, MONOHYDRATE CUPRIC CHLORATE Silver chloride Silver iodide SILVER(I) SULFIDE SILVER BROMIDE SILVER NITRITE Silver cyanide N/A Ammonium chlorate Calcium chloride hexahydrate Ag(I){9,10-bisdiphenylphosphinoethylanthracene} ClO4 [Ag(I){9,10-bisdiphenylphosphinomethyl(N-propaminomethyl)anthracene}ClO4]2 SILVER PERCHLORATE SILVER CHLORATE SILVER PERCHLORATE HYDRATE Anthraceno-Diphosphine-Silver(I) Complex Ag2(ClO4)2[2,6-bis(N-benzylamino)-3,5-bis(N-diphosphino)pyridine]2

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