ChemicalBook Product Catalog Chemical Reagents Organic reagents Phosphine ligand 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Basic information
Product Name:1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Synonyms:DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II);1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE;1,2-Bis(diphenylphosphino)ethane nickel(II) chloride,98%;Dichloro[1,2-ethanediylbis[diphenylphosphine]-P,P']nickel;1.2-Bis(dipheny phosphine) ethane nickel(II)chloride
CAS:14647-23-5
MF:C26H24Cl2NiP2
MW:528.02
EINECS:629-489-4
Product Categories:API intermediates;Catalysis and Inorganic Chemistry;Chemical Synthesis;Ni;Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal-phosphine complexes
Mol File:14647-23-5.mol
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Structure
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties
Melting point 263-265 °C(lit.)
storage temp. Inert atmosphere,2-8°C
solubility Chloroform, Methanol (Sparingly)
form crystal
color orange
Water Solubility insoluble
Exposure limitsNIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:Hygroscopic
CAS DataBase Reference14647-23-5(CAS DataBase Reference)
Safety Information
Hazard Codes T,Xn
Risk Statements 45-20/21/22-36/37/38-42/43-40
Safety Statements 53-22-26-36-45-52
WGK Germany 3
TSCA No
HS Code 29319090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Usage And Synthesis
Chemical PropertiesOrange to red crystalline powder
UsesDichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.
Usessuzuki reaction
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Preparation Products And Raw materials
Raw materialsEthanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Triphenylphosphine-->1,2-Dichloroethane-->Lithium-->1,2-Dibromoethane-->Nickel(II) chloride hexahydrate-->Diphenylphosphine
1,1'-Bis(diphenylphosphino)ferrocene Nickel chloride 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE Diphenylphosphine Diphenylphosphine oxide ETHANE-D Bis(diphenylphosphino)ethane-nickel(II)chloride 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Hexafluoroethane 1,2-BIS(PHENYLPHOSPHINO)ETHANE Choline chloride DICHLOROBIS(TRIMETHYLPHOSPHINE)NICKEL(II) Chlorodiphenylphosphine Ammonium chloride 1,2-Bis(diphenylphosphino)ethane Nickel chloride diphenyl(2-phosphinoethyl)phosphine 2-​[[(2-​ethylphenyl)​(2-​hydroxyethyl)​amino]​methyl]​-​3,​3-​difluoro-Propanenitrile
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