Fluazifop-butyl

Fluazifop-butyl Basic information
Product Name:Fluazifop-butyl
Synonyms:Fluazifop-butyl solution;2-[4-(5-Trifluoromethylpyridin-2-yloxy)phenoxy]propionic acid butyl ester;2-[4-[(5-Trifluoromethyl-2-pyridinyl)oxy]phenoxy]propionic acid butyl ester;fluazifop-butyl (ISO) butyl (RS)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate;2-[4-[[5-(trifluoromethyl)-2-pyridyl]oxy]phenoxy]propionic acid butyl ester;butyl 2-[4-[5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoate;Fluazifop-butyl 250mg [69806-50-4];FUSILADE
CAS:69806-50-4
MF:C19H20F3NO4
MW:383.36
EINECS:274-125-6
Product Categories:Alpha sort;E-GAlphabetic;F;FA - FLEnvironmental Standards;Herbicides;MetabolitesPesticides&Metabolites;Pesticides&Metabolites;Phenoxy structure
Mol File:69806-50-4.mol
Fluazifop-butyl Structure
Fluazifop-butyl Chemical Properties
Melting point 13°C
Boiling point bp0.05 167°
density 1.2100
Fp 2 °C
storage temp. 0-6°C
form neat
pka0.78±0.22(Predicted)
Water Solubility 536.6ug/L(temperature not stated)
Merck 13,4142
EPA Substance Registry SystemFluazifop-butyl (69806-50-4)
Safety Information
Hazard Codes T,N,Xn,F
Risk Statements 61-50/53-36-20/21/22-11
Safety Statements 53-45-60-61-36-26-16
RIDADR UN3082 9/PG 3
WGK Germany 3
RTECS UA3000000
HS Code 29333990
Hazardous Substances Data69806-50-4(Hazardous Substances Data)
MSDS Information
Fluazifop-butyl Usage And Synthesis
Chemical PropertiesPale straw-colored, odorless liquid.
Chemical PropertiesPale yellow liquid. Odorless.
UsesFood additive; herbicide; agricultural chemical.
UsesFluazifop-butyl-d9 is the labeled version of Fluazifop-butyl (F407433), which is often found in herbicidal and fungicidal mixture compositions.
DefinitionChEBI: Butyl 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoate is a carboxylic ester resulting from the formal condensation of the carboxy group 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid with the hydroxy group of butan-1-ol. It is a carboxylic ester, an organofluorine compound, a member of pyridines and an aromatic ether. It is functionally related to a 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid and a butan-1-ol.
General DescriptionA pale straw colored liquid. Selective herbicide.
Air & Water ReactionsSlightly soluble in water.
Reactivity ProfileFLUAZIFOP-BUTYL is a trimethyl phenoxy pyridine ester. May react with acids to liberate heat. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. May generate heat with caustic solutions. Genreates flammable hydrogen with alkali metals and hydrides.
HazardModerately toxic by ingestion.
Agricultural UsesHerbicide: Fluazifop-butyl is a selective post-emergence herbicide. Its principal uses in California is on rights-of-way, landscapes, almonds, cotton, and outdoor container nurseries. Not approved for use in EU countries. Not registered for use in the U.S. Used in southeast Asia. There are 18 global suppliers.
Trade nameFUSILADE®[C]; FUSILADE® MAX (P-butyl); FUSION®; GRASS-B-GONE®; Greencrop; HACHE UNO SUPER®; HORIZON®; ICI-A0009®; ONESIDE®; ONESIDE EC®; ORNAMEC®; PP 009®; SL-236®; TF 1169®; TS-7236®; TORNADO®
Potential ExposureFluazifop-butyl is a selective post emergence aryloxyphenoxypropionate/organofluorine herbi cide. Its principal uses In California is on rights-of-way, landscapes, almonds, cotton, and outdoor container nurseries.
Metabolic pathwayFluazifop butyl as a thin film on glass is photorearranged by UV irradiation to the isomer butyl-(RS)-2-[4-hydroxy-3-(5-trifluoromethyl-2- pyridyl)phenoxy]propionate. Plants of both resistant and susceptible populations of Digitaria sanguinalis rapidly hydrolyze 14C-fluazifop butyl to corresponding acid in leaves, but fluazifop acid is metabolized to other compounds at a more rapid rate in the resistant plants. An enhanced metabolism of toxophore, fluazifop acid is a likely mechanism of resistance in this population. The plants of putative resistant and susceptible population of Digitaria sanguinalis (L.) Scop had survived the application of 212 g/ha fluazifop-P-butyl in the year of collection.
Waste DisposalIn accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Containers must be dis posed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.
Fluazifop-butyl Preparation Products And Raw materials
Raw materialsHydroquinone-->2-Chloro-5-trifluoromethylpyridine-->2-Chloro-5-trichloromethylpyridine-->Butyl propionate
2-[4-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxyphenoxy]propanoic acid FLUAZIFOP-BUTYL:BUTYL 2-[4-(5-TRIFLUOROMETHYL-2-PYRIDYLOXY)-PHENOXY]PROPIONATE,Fluazifop-butyl E.C. FLUAZIFOP-BUTYL (PHENYL-UL-14C) FLUAZIFOP-BUTYL SOLUTION 100UG/ML IN TOLUENE 1ML Fluazifop-butyl Paraformaldehyde FLUAZIFOP-BUTYL SOLUTION 100 NG/MYL IN Diclofop-methyl Butyl propionate FLUAZIFOP PARAFORMALDEHYDE-D2 Diclofop FLUAZIFOP-BUTYL SOLUTION 100UG/ML IN ACETONITRILE 1ML

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