ChemicalBook Product Catalog Chemical Reagents Organic reagents Aromatic ketones 3'-Chloroacetophenone

3'-Chloroacetophenone

3'-Chloroacetophenone Basic information
Uses
Product Name:3'-Chloroacetophenone
Synonyms:M-CHLOROACETOPHENONE;1-(3-CHLOROPHENYL)ETHANONE;1-(3-chlorophenyl)-ethanon;3'-Chloroacetylphenone;Ethanone, 1-(3-chlorophenyl)-;3'-Chloroacetophenone 1-(3-Chlorophenyl)ethanone 3-Chloroacetophenone;3-Chloroacetophenone, 98+%;3'-CHLOROACETOPHENONE
CAS:99-02-5
MF:C8H7ClO
MW:154.59
EINECS:202-721-8
Product Categories:Aromatic Acetophenones & Derivatives (substituted);Adehydes, Acetals & Ketones;Chlorine Compounds;C7 to C8;Carbonyl Compounds;Ketones
Mol File:99-02-5.mol
3'-Chloroacetophenone Structure
3'-Chloroacetophenone Chemical Properties
Boiling point 227-229 °C(lit.)
density 1.191 g/mL at 25 °C(lit.)
refractive index n20/D 1.550(lit.)
Fp 221 °F
storage temp. Sealed in dry,Room Temperature
form Liquid
color Clear colorless to yellow
Specific Gravity1.191
Sensitive Lachrymatory
BRN 636318
InChIKeyUUWJBXKHMMQDED-UHFFFAOYSA-N
CAS DataBase Reference99-02-5(CAS DataBase Reference)
NIST Chemistry ReferenceAcetophenone, 3'-chloro-(99-02-5)
EPA Substance Registry SystemEthanone, 1-(3-chlorophenyl)- (99-02-5)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-36-20/21/22
Safety Statements 26-36-37/39-36/37/39-13-7/9
RIDADR UN 3416 6.1/PG 2
WGK Germany 3
F 19
Hazard Note Harmful/Irritant/Lachrymatory
TSCA Yes
HazardClass 6.1
PackingGroup II
HS Code 29147090
MSDS Information
ProviderLanguage
3'-Chloroacetophenone English
SigmaAldrich English
ACROS English
ALFA English
3'-Chloroacetophenone Usage And Synthesis
Uses3'-Chloroacetophenone can be used as a raw material for pharmaceutical synthesis, mainly for the synthesis of carbamazepine, a drug for the treatment of epilepsy, and as an intermediate for fine chemicals, pesticides, etc.
Chemical Propertiesclear colourless to yellow liquid
Uses3’-Chloroacetophenone is usd in the synthesis of GABA-AT inhibitors. Also used in the synthesis of antimycobacterial studies.
Synthesis Reference(s)The Journal of Organic Chemistry, 60, p. 2361, 1995 DOI: 10.1021/jo00113a013
General DescriptionThe activity of strain, Saccharomyces cerevisiae B5, on the reduction of 3′-chloroacetophenone was studied.
3'-Chloroacetophenone Preparation Products And Raw materials
Preparation Products3-(3-Chlorophenyl)-1H-pyrazole-5-carbohydrazide ,97%-->3-(3-Chlorophenyl)-1H-pyrazole-5-carboxamide ,97%-->5-(3-CHLOROPHENYL)-1H-PYRAZOLE-3-CARBOXYLIC ACID-->Ethyl 3-(3-chlorophenyl)-1H-pyrazole-5-carboxylate ,97%-->3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER-->Ethanone,1-(2-amino-5-chlorophenyl)--->1-(5-CHLORO-2-NITROPHENYL)-1-ETHANONE-->3-CHLOROPHENACYL BROMIDE-->2,3'-Dichloroacetophenone-->3'-IODOACETOPHENONE-->(E)-1-(3-Chlorophenyl)-3-diMethylaMinopropenone-->Hydrazinecarboxamide,2-[1-(3-chlorophenyl)ethylidene]-
4'-Methoxyacetophenone 4'-Bromoacetophenone Chloroacetic acid 3-Aminoacetophenone 3-Chlorobenzyl cyanide 4-Nitroacetophenone Difluorochloromethane 2',6'-Dichloroacetophenone Acetophenone 2,4-Dichloro-5-fluoroacetophenone 2',4'-Dichloroacetophenone L-PICEIN 3'-(Trifluoromethyl)acetophenone CHLOROACETOPHENONE Dichloroacetonitrile 4'-CHLOROACETOPHENONE,4-CHLOROACETOPHENONE 3-Methoxyacetophenone 2',4'-Dichloro-α-chloroacetophenone
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